Affiliations 

  • 1 Faculty of Electronic Engineering Technology, Universiti Malaysia Perlis (UniMAP), Pauh Putra Campus, 02600 Arau, Perlis, Malaysia
  • 2 Faculty of Mechanical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Pauh Putra Campus, 02600 Arau, Perlis, Malaysia. Electronic address: [email protected]
  • 3 Faculty of Mechanical Engineering Technology, Universiti Malaysia Perlis (UniMAP), Pauh Putra Campus, 02600 Arau, Perlis, Malaysia
  • 4 Faculty of Electronic Engineering Technology, Universiti Malaysia Perlis (UniMAP), Pauh Putra Campus, 02600 Arau, Perlis, Malaysia. Electronic address: [email protected]
  • 5 Department of Mechanical Engineering, Najran University, King AbdulAziz Road, PO Box 1988, Najran, Saudi Arabia. Electronic address: [email protected]
  • 6 Faculty of Electronic Engineering Technology, Universiti Malaysia Perlis (UniMAP), Pauh Putra Campus, 02600 Arau, Perlis, Malaysia. Electronic address: [email protected]
Int J Biol Macromol, 2021 Sep 30;187:43-53.
PMID: 34271052 DOI: 10.1016/j.ijbiomac.2021.07.069

Abstract

A packaging material that is environment-friendly with excellent mechanical and physicochemical properties, biodegradable and ultraviolet (UV) protection and thermal stability was prepared to reduce plastic waste. Six different concentrations of Pennisetum purpureum/Napier cellulose nanowhiskers (NWCs) (i.e. 0, 0.5, 1.0, 1.5, 2.0, and 3.0 wt%) were used to reinforce polylactic acid (PLA) by a solvent casting method. The resulting bionanocomposite film samples were characterised in terms of their morphology, chemical structure, crystallinity, thermal degradation and stability, light transmittance, water absorption, biodegradability, and physical and mechanical properties. Field-emission scanning electron microscopy showed the excellent dispersion of NWC in the PLA matrix occurred with NWC concentrations of 0.5-1.5 wt%. All the bionanocomposite film samples exhibited good thermal stability at approximately 343-359 °C. The highest water absorption was 1.94%. The lowest transparency at λ800 was 16.16% for the PLA/3.0% NWC bionanocomposite film, which also has the lowest UVA and UVB transmittance of 7.49% and 4.02%, respectively, making it suitable for packaging materials. The PLA/1.0% NWC film exhibited the highest crystallinity of 50.09% and high tensile strength and tensile modulus of 21.22 MPa and 11.35 MPa, respectively.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.