Pembentukan lapisan sempadan halaju dan terma yang dirangsang oleh aliran bebas bersebelahan plat tegak dengan suhu permukaan malar dikaji. Persamaan-persamaan menakluk dalam bentuk persamaan pembezaan separa diturunkan kepada persamaan-persamaan pembezaan biasa dengan penjelmaan keserupaan, sebelum diselesaikan secara berangka. Kedua-dua aliran membantu dan aliran menentang dipertimbangkan. Didapati bahawa penyelesaian adalah unik bagi aliran membantu, manakala penyelesaian dual wujud bagi aliran menentang. Kadar pemindahan haba pada permukaan didapati meningkat dengan peningkatan kedua-dua daya keapungan dan nombor Prandtl.
Aliran lapisan sempadan mantap dua matra bersebelahan titik genangan pada permukaan meregang dalam bendalir mikropolar dengan fluks haba permukaan boleh ubah dikaji. Halaju regangan dan halaju aliran bebas diandaikan berubah secara linear dari titik genangan. Persamaan dalam bentuk persamaan pembezaan separa dijelmakan kepada persamaan pembezaan biasa menggunakan penjelmaan keserupaan dan diselesaikan secara berangka menggunakan skim beza-terhingga yang dikenali sebagai kaedah kotak Keller. Kedua-dua aliran membantu dan aliran menentang dipertimbangkan. Lapisan sempadan terbentuk apabila halaju aliran bebas melebihi halaju regangan, sebaliknya, lapisan sempadan yang terbalik terbentuk apabila halaju aliran bebas kurang daripada halaju regangan. Keputusan berangka menunjukkan bahawa daya seretan berkurangan bagi bendalir mikropolar berbanding dengan bendalir Newtonan, dan ini seterusnya mengurangkan kadar pemindahan haba pada permukaan.
Satu kajian keratan rentas telah dijalankan untuk melihat kesan pendedahan haba ke atas perubahan fisiologi di kalangan pekerja lelaki sebuah kilang pembuatan komponen otomotif di Shah Alam, Selangor. Seramai 46 orang yang berkerja di bahagian foundri telah dipilih sebagai responden kajian. Pemboleh ubah yang dikaji adalah WBGT Dalaman, kadar haba metabolik, suhu teras badan, tekanan darah, denyutan nadi dan kadar denyutan nadi. Hasil kajian mendapati nilai min WBGT Dalaman di bahagian operasi foundri adalah sebanyak 28.96 0C. Pekerja foundri terdedah kepada haba semasa
proses peleburan besi, proses memasukkan silika dah debu besi ke dalam acuan pembentukan, dan pembentukan teras. Purata masa pengukuran yang paling singkat adalah selama 2 jam dan 8 jam untuk keseluruhan tempoh pendedahan. Ujian Bonferroni menunjukkan terdapat perbezaan yang signifikan di antara suhu teras badan sebelum syif bermula dengan 2 jam selepas syif bermula (p = 0.05) dan di antara sebelum syif bermula dengan selepas tamat syif 8 jam bekerja (p < 0.001). Terdapat perkaitan yang lemah di antara suhu teras badan dengan kadar denyutan nadi sebelum syif bermula (r = 0.293, p = 0.048) dan di antara suhu teras badan dengan tekanan darah sistolik selepas tamat syif 8 jam bekerja (r = 0.309, p =0.036). Kadar denyutan nadi responden adalah berada di antara julat 51 hingga 98 denyutan perminit, menunjukkan tidak terdapat tuntutan aktiviti kerja yang berlebihan ke atas fisiologi. Min suhu teras badan (36.37 ± 0.53 0C) dan kadar denyutan nadi (74.50 ± 10.10 per minit) selepas tamat syif 8 jam menunjukkan pekerja mempunyai kawalan
tubuh badan yang baik terhadap pendedahan haba. Tiga daripada empat seksyen kerja yang dikaji mempunyai bacaan WBGT Dalaman melebihi 28 0C (ACGIH TLV). Pekerja terdedah kepada tegasan haba yang sederhana sepanjang kajian ini berlangsung, walaubagaimanapun, suhu teras badan, kadar denyutan nadi dan tekanan darah masih tidak mencapai tahap tegangan kepada fisiologi.
Sifat pengelatinan salutan semasa peringkat awal penggorengan pada beberapa suhu yang berbeza telah dikaji. Nuget ayam, sebagai substrat, dicelup ke dalam cecair penyalut dan kemudiannya digoreng pada 150, 165 dan 180oC selama 0, 6, 18 dan 30s. Selepas penggorengan, bahagian salutan dan substrat dianalisis secara berasingan untuk kandungan lembapan. Bahagian salutan juga dianalisis untuk suhu permulaan (To), puncak (Tp) dan akhir (Te) serta entalpi pengelatinan. Keputusan menunjukkan tiada kesan ketara oleh suhu penggorengan terhadap kandungan lembapan kedua-dua bahagian salutan dan substrat. Tetapi, terdapat pola pengurangan kandungan lembapan dengan peningkatan masa penggorengan sehingga 30s untuk setiap suhu yang dikaji. Tiada kesan ketara oleh suhu penggorengan terhadap To, Tp dan Te. Tetapi, penggorengan pada 180 oC menghasilkan darjah pengelatinan yang lebih tinggi selepas 6s. Peningkatan kadar pengelatinan apabila digoreng pada suhu yang lebih tinggi boleh disebabkan oleh peningkatan kadar perpindahan haba semasa penggorengan.
Analisis terhadap sistem sel bahan api 5kW ini merangkumi analisis eksergeokonomi iaitu mengkaji kebolehdapatan tenaganya dan seterusnya analisis kesan ekonominya diambil kira selepas kebolehdapatan tenaganya dilakukan. Sistem sel bahan api dalam kes kajian terdiri daripada unit pemperosesan hidrogen dan unit pemprosesan bahan api dengan unit pemprosesan haba terdiri daripada reaktor auto-terma (ATR), reaktor pemindahan gas air (WGS), satu modul seramik (TMC) dan penjerap tekanan berayun (PSA). Stek sel bahan api penukar proton membran (PEMFC) adalah sumber penjana kuasa yang utama. Didapati modul seramik TCM dan penjerap PSA mempunyai kecekapan kebolehdapatan tenaga yang sangat rendah iaitu 0.29% dan 0.09%. Reaktor auto-terma dan stek sel bahan api pula adalah lebih tinggi iaitu 22.44% dan 31.97%, dan nilai-nilai ini adalah lebih kurang sama dengan kajian lain. Daripada pengiraan, didapati eksergoekonomi bagi 5 kW keseluruhan sistem sel bahan api kajian ini adalah sebanyak RM4756.62 per GJ. Analisis eksergoekonomi juga menunjukkan bahawa sistem sel bahan api akan menjadi lebih berekonomi jika kos operasi dan penyelenggaraan dan kos bahan api dapat dikurangkan.
The conversion of carbon-rich biomass into valuable material is an environmental-friendly approach for its reutilization. In this study, coconut shell-derived biochar, graphitic carbon nitride (g-C3N4), g-C3N4/biochar, titanium dioxide (TiO2)/biochar, zinc oxide (ZnO)/biochar, and ferric oxide (Fe2O3)/biochar were synthesized and characterized by using scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), surface area analysis, UV-Vis diffuse reflectance spectroscopy (DRS), and zeta potential analysis. The g-C3N4 or metal oxide particles were found to be well-distributed on the coconut shell-derived biochar with the improvement in thermal stability and enlargement of specific surface area. A great reduction in band gap energy was observed in the composite materials after incorporating with the biochar. Among different biochar composites, g-C3N4/biochar was found to have the highest photocatalytic activity. The interactive effect of parameters such as catalyst dosage, peroxymonosulfate (PMS) oxidant dosage, and solution pH on the photocatalytic degradation of methyl orange was investigated using the response surface methodology (RSM). The highest photocatalytic degradation efficiency (96.63%) was achieved at catalyst dosage of 0.75 g/L, oxidant dosage of 0.6 mM, and solution pH 3 after 30 min.
The current research concentrated on the Co-precipitation synthesis of g-C3N4 (CN), ZnO, ZnO/CN, and Co-doped ZnO/CN nanocomposite, as well as the solar light enhanced photocatalytic treatment of Reactive Red 120 (RR120) from genuine wool textile effluent. The 3D flower-like structure of Co-doped ZnO distributed on the surface of CN thin sheets, according to structural studies employing XRD and SEM examinations Electrochemical experiments exhibited that the Co-doped ZnO/CN nanocomposite has a large electroactive surface area. The optical band-gap values of CN, ZnO, ZnO/CN, and Co-doped ZnO/CN nanocomposites were 2.68, 3.13, 2.38, and 2.23 eV, respectively, according to optical characterizations. The synergistic effects and heterojunction produced by Co-doped ZnO and CN can be linked to the narrow gap in nanocomposites. After 75, 60, 50, and 40 min of exposure to solar light, photocatalytic degradation assays for 250 mL of 20 mg/L RR120 solution in the presence of CN, ZnO, ZnO/CN, and Co-doped ZnO/CN nanocomposites demonstrated 100% dye treatment. The applicability of photocatalysts for decolorization of 250 mL of 10 mg/L RR120 prepared from actual wool textile wastewater was investigated, and the results showed that Co-doped ZnO/CN nanocomposites for treatment of RR120 from actual wool textile wastewater were highly efficient at photocatalytic degradation.
The primary responsibility for continuously discharging toxic organic pollutants into water bodies and open environments is the increase in industrial and agricultural activities. Developing economical and suitable methods to continuously remove organic pollutants from wastewater is highly essential. The aim of the present research was to apply response surface methodology (RSM) and artificial neural networks (ANNs) for optimization and modeling of photocatalytic degradation of acid orange 7 (AO7) by commercial TiO2-P25 nanoparticles (TNPs). Dose of TNPs, pH, and AO7 concentration were selected as investigated parameters. RSM results reveal the reflective rate of AO7 removal of ~ 94.974% was obtained at pH 7.599, TNP dose of 0.748 g/L, and AO7 concentration of 28.483 mg/L. The resulting quadratic model is satisfactory with the highest coefficient of determination (R2) between the predicted and experimental data (R2 = 0.98 and adjusted R2 = 0.954). On the other hand, ANNs were successfully employed for modeling of AO7 degradation process. The proposed ANN model was absolutely fitted with experimental results producing the highest R2. Furthermore, root mean square error (RMSE), mean average deviation (MAD), absolute average relative error (AARE), and mean square error (MSE) were examined more to compare the predictive capabilities of ANN and RSM models. The experimental data was well fitted into pseudo-first-order and pseudo-second-order kinetics with more accuracy. Thermodynamic parameters, namely enthalpy, entropy, Gibbs' free energy, and activation energy, were also evaluated to suggest the nature of the degradation process. The increase of temperature was analyzed to be more suitable for the fast removal of AO7 over TNPs. Graphical abstract.
One half of the molecule of the title complex, [Mn(C(14)H(13)N(4)S)(2)], is related to the other half by a twofold axis passing through the Mn atom. This high-spin Mn atom is six-coordinated, in an octahedral geometry, by the azomethine N, the pyridyl N and the thiolate S atom of two planar 1-(pyridin-2-yl)ethanone N(4)-phenylthiosemicarbazone ligands. In the crystal, the molecules are interconnected by N-H.S and C-H.N interactions, forming a three-dimensional network.
Dalam makalah ini, masalah aliran genangan dalam bendalir mikrokutub terhadap permukaan mencancang yang telap dengan fluks haba boleh ubah dipertimbangkan. Dengan menggunakan penjelmaan keserupaan, persamaan asas yang menakluk aliran bendalir dan pemindahan haba dijelmakan kepada satu set persamaan perbezaan biasa. Persamaan yang dijelmakan tertakluk kepada syarat-syarat sempadan yang berkaitan kemudiannya diselesaikan secara berangka menggunakan kaedah tembakan. Kesan parameter sedutan/semburan fw ke atas profil halaju dan suhu serta pekali geseran kulit dan nombor Nusselt setempat diperoleh dan dibincangkan. Keputusan berangka menunjukkan bahawa penyelesaian dual wujud dalam kedua-dua aliran membantu dan aliran menentang.
Penyelesaian berangka bagi masalah aliran lapisan sempadan olakan bebas mantap terhadap silinder bulat mengufuk yang dijanakan oleh pemanasan Newtonan, iaitu pemindahan haba dari permukaan berkadar langsung dengan suhu permukaan setempat, dipertimbangkan. Persamaan lapisan sempadan terjelma diselesaikan secara berangka dengan suatu skim berangka beza terhingga tersirat yang dikenali sebagai kaedah kotak Keller. Penyelesaian berangka diperoleh bagi pekali geseran kulit, pekali pemindahan haba setempat, suhu dinding serta profil halaju dan suhu. Ciri-ciri aliran dan pemindahan haba bagi suatu julat nilai nombor Prandtl yang besar dianalisis dan dibincangkan.
Kajian ini bertujuan untuk memilih kaedah terbaik daripada sebelas kaedah pengiraan Escherichia coli dalam masakan ayam. Kaedah-kaedah tersebut adalah piring curahan, piring sebaran, piring titisan, PetrifilmTM, tiga jenis pemiringan terus dan empat jenis kaedah bilangan paling mungkin (MPN). Perbandingan kaedah dijalankan mengikut prosedur ISO 16140. Setiap strain E. coli (ATCC 25922, IMR 1/3 107B dan IMR E243) telah diinokulasikan ke dalam lima jenis masakan ayam bagi mendapatkan kepekatan bakteria sehingga 105 cfu/g. Perlakuan haba dibuat pada 55oC selama
4-6 min bagi mewujudkan persekitaran yang seakan-akan sama seperti makanan tersebut dihidangkan sebaik sahaja selepas dimasak. Analisis statistik Regressi Kaedah Kuasa Dua Terkecil (KKDT) dijalankan bagi membandingkan sebelas kaedah pengiraan E. coli. Nilai kecerunan (m) yang signifikan (p < 0.05) pada kesemua Graf KKDT membawa maksud kesemua kaedah adalah serupa daripada segi kejituan, korelasi, dan ketepatan relatif. Oleh itu, penilaian praktikal turut dipertimbangkan bagi menentukan tiga kaedah terbaik bagi pengiraan E. coli dalam masakan ayam. Piring curahan, PetrifilmTM dan piring titisan adalah lebih praktikal berbanding lapan kaedah yang lain.
Herein, we systematically reported the capability of T. harzianum RY44 for decolorization of Mordant orange-1. The fungi strains were isolated from the Universiti Teknologi Malaysia tropical rain forest. For initial screening, the decolorization was conducted using 50 strains of the fungi for 20 days incubation time and the best performance was selected. Then, the decolorization capability and fungal biomass were evaluated using different dye concentrations, namely, 0, 50, 75 and 100 ppm. Effects of the carbon sources (fructose, glucose, and galactose), nitrogen sources (ammonium nitrate, ammonium sulfate and yeast extract), surfactant (tween 80), aromatic compounds (benzoic acid, catechol and salicylic acid), and pH on the decolorization efficiency were examined. This study has found that the employed carbon sources, nitrogen sources, and aromatic compounds strongly enhance the decolorization efficiency. In addition, increasing the surfactant volume and pH generally decreased the decolorization efficiencies from 19.5 to 9.0% and 81.7 to 60.5%, respectively. In the mechanism philosophy, the present work has found that Mordant orange-1 were initially degraded by T. harzianum RY44 to benzoic acid and finally transformed into salicylic acid.
Maleic anhydride was reacted with p-aminophenol and p-toluidine in the presence of di-phosphorus pentoxide (P₂O₅) as a catalyst to produce two compounds: N-(4-hydroxy-phenyl)maleimide (I) and N-(4-methylphenyl)maleimide (II). The new azo compounds I(a-c) and II(a-c) were prepared by the reaction of I and II with three different aromatic amines, namely aniline, p-aminophenol and p-toluidine. The structures of these compounds were confirmed by CHN, FT-IR, ¹H-NMR, ¹³C-NMR, mass spectrum and UV/Vis spectroscopy.
This study was to investigate the mineralization of wastewater containing methyl orange (MO) in integrated anaerobic-aerobic biofilm reactor with coconut fiber as bio-material. Different aeration periods (3h in phase 1 and 2; 3, 6 and 15 h in phase 3; 24 h in phase 4 and 5) in aerobic chamber were studied with different MO concentration 50, 100, 200, 200 and 300 mg/L as influent from phase 1-5. The color removals estimated from the standard curve of dye versus optical density at its maximum absorption wavelength were 97%, 96%, 97%, 97%, and 96% and COD removals were 75%, 72%, 63%, 81%, and 73% in phase 1-5, respectively. The MO decolorization and COD degradation followed first-order kinetic model and second-order kinetic model, respectively. GC-MS analysis indicated the symmetrical cleavage of azo bond and the reduction in aromatic peak ensured the partial mineralization of MO.
Microbial fuel cells (MFCs) represent an emerging technology that focuses on power generation and effluent treatment. This review compiles articles related to MFCs using azo dye as the substrate. The significance of the general components in MFCs and systems of MFCs treating azo dye is depicted in this review. In addition, degradation of azo dyes such as Congo red, methyl orange, active brilliant red X-3B, amaranth, reactive blue 221, and acid orange 7 in MFCs are summarized. Further exploration and operational modification are suggested to address the challenges of complete removal of azo dye with maximum power generation in an MFC. In addition, a sequential treatment system with MFCs is suggested for complete mineralization of azo dye.
In this work, an activated electric arc furnace slag (A-EAFS) was investigated as an effective Fenton catalyst for the photodegradation of methylene blue (MB) and acid blue 29 (AB29). Fourier transform infrared spectroscopy and UV-visible absorption analyses indicated that A-EAFS offers additional Fe3O4 because of the changes in the iron oxide phase and the favorable response to visible light. It has been found that the highest degradation efficiency can reach up to 94% for MB under optimal conditions of 1 g L-1 of A-EAFS, 20 mM H2O2, and pH 3. The optimal conditions for AB29 were 0.1 g L-1 A-EAFS, 4 mM H2O2, and pH 3 to reach 98% degradation efficiency. Visible light enhanced the degradation of both dyes. In addition, A-EAFS, could be easily separated magnetically, exhibited good chemical stability after seven successive photodegradation cycles.
This study explored the influence of azo dye concentration, salinity (with and without aeration) and nitrate concentration on bioelectricity generation and treatment performance in the up-flow constructed wetland-microbial fuel cell (UFCW-MFC) system. The decolourisation efficiencies were up to 91% for 500 mg/L of Acid Red 18 (AR18). However, the power density declined with the increment in azo dye concentration. The results suggest that the combination of salinity and aeration at an optimum level improved the power performance. The highest power density achieved was 8.67 mW/m2. The increase of nitrate by 3-fold led to decrease in decolourisation and power density of the system. The findings revealed that the electron acceptors (AR18, nitrate and anode) competed at the anodic region for electrons and the electron transfer pathways would directly influence the treatment and power performance of UFCW-MFC. The planted UFCW-MFC significantly outweighed the plant-free control in power performance.
Phosphorylated chitosan (P-CS) was successfully synthesized using a facile experimental setup of hydrothermal method that was applied to the adsorption of anionic Acid Red 88 (AR88) from aqueous media. The adsorption process obeyed the pseudo-second-order (PSO) kinetic model. In contrast, the adsorption isotherm conformed to the Langmuir model, with the maximum adsorption capacity (qm = 230 mg g-1) at 303 K. Both external and intraparticle diffusion strongly influenced the rate of adsorption. The insights from this study reveal that P-CS could be easily prepared and regenerated for reusability applications. The adsorption mechanism and intermolecular interaction between P-CS and AR 88 were investigated using Fourier transform infrared (FTIR) spectroscopy and calculations via Density Functional Theory (DFT). The key modes of adsorption for the P-CS/AR 88 system are driven by electrostatic attractions, H-bonding, and n-π interactions. The findings herein reveal that P-CS is a promising adsorbent for the removal of anionic dyes such as AR88 or similar pollutants from water.
The treatment of single and binary azo dyes, as well as the effect of the circuit connection, aeration, and plant on the performance of UFCW-MFC, were explored in this study. The decolorization efficiency of Remazol Yellow FG (RY) (single dye: 98.2 %; binary dye: 92.3 %) was higher than Reactive Black 5 (RB5) (single: 92.3 %; binary: 86.7 %), which could be due to monoazo dye (RY) requiring fewer electrons to break the azo bond compared to the diazo dye (RB5). In contrast, the higher decolorization rate of RB5 in binary dye indicated the removal rate was affected by the electron-withdrawing groups in the dye structure. The closed circuit enhanced about 2% of color and 4% of COD removal. Aeration improved the COD removal by 6%, which could be contributed by the mineralization of intermediates. The toxicity of azo dyes was reduced by 11-26% and the degradation pathways were proposed. The dye removal by the plants was increased with a higher contact time. RB5 was more favorable to be uptook by the plant as RB5 holds a higher partial positive charge. 127.39 (RY), 125.82 (RB5), and 58.66 mW/m3 (binary) of maximum power density were generated. The lower power production in treating the binary dye could be due to more electrons being utilized for the degradation of higher dye concentration. Overall, the UFCW-MFC operated in a closed circuit, aerated, and planted conditions achieved the optimum performance in treating binary azo dyes containing wastewater (dye: 87-92%; COD: 91%) compared to the other conditions (dye: 83-92%; COD: 78-87%).