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  1. Shamini Rengasamy, Tan, Yik Yee
    MyJurnal
    Two EU directives which are RoHS and WEEE have restricted the usage of certain hazardous substances in
    electrical and electronic equipment. This has led to the introduction of green compound which is halogen free. The
    non-halogenated molding compound with different recipes was developed by compound manufacturers without
    compromising the reliability performance of electronic packages. The focus, often, has been on product reliability
    performance while qualifying new materials which overlook relevant safety and health concerns that might incur
    during the production stage. This paper is intended to study the forming of crystalline deposits which are found at
    the exhaust inlet of the Post Mold Cure Oven (PMC) arising from the usage of this green compound. The writers will
    investigate the underlying reasons and the impact on the work environment and the potential risk on health. From the
    initial evaluation result, the writers have indentified Compound A as the cause of this deposition. Data analyzed from
    the Thermo-Gravimetric Analysis (TGA) revealed higher weight loss which was 0.26% for compound A compared to
    other green compounds which are also used. Differential Scanning Calorimetric (DSC) test shows melting temperature
    of crystallized particle at 139°C while cold crystallization temperature at 80°C. The temperature in the interior of the
    oven is 180°C while the temperature at the exhaust inlet which is exposed to room temperature, and thus, providing
    the opportunity for this deposition. Further study carried out using Fourier Transform Infrared (FTIR) spectroscopy
    on one of the ingredient of the green compound (material C) observed a 95% spectrum matching compared to the
    crystallized particle. Material C is a catalyst added to the mold compound for epoxy-phenolic reaction. It is also
    considered to have the capability to enhance flame retardation. This paper will discuss in detail the characteristics of
    Compound A green compound and its impact on human and environment.
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