This paper is focussed on conductivity and dielectric properties of Poly (vinyl) chloride (Pvc)- ammonium triflate (NH4CF3SO3) - butyltrimethyl ammonium bis (trifluoromethyl sulfonyl) imide (Bu3MeNTf2N) ionic liquid, electrolyte system. The electrolyte is prepared by solution cast technique. In this work, the sample containing 30 wt. % NH4CF3SO3 exhibits the highest room temperature conductivity of 2.50 x 10-7 S cm' . Ionic liquid is added in various quantities to the 70 wt. % Pvc-30 wt. % NH4CF3SO3 composition in order to enhance the conductivity of the sample. The highest conductivity at room temperature is obtained for the sample containing 15 wt. % Bu3MeNTf2N with a value of 1.56 x 10 -4 S cm' . The effects of ionic liquid addition on the frequency dependent dielectric properties of PVC based electrolytes is investigated by electrochemical impedance spectroscopy (Eis) at room temperature. The values of dielectric constant were found to increase with increasing conductivity of the samples. Analysis of the ac conductivity data showed the electrolytes to be of the non-Debye type.
The effect of graphene content on the structure and conductivity of an eco-friendly cellulose/ graphene (CG) composite was investigated. Different compositions of graphene content from 0 to 70 wt. % were prepared using the sol-gel method. Ionic liquids 1-butyl-3-methyl-imidazolium chloride was used to disperse graphene between the cellulose. The investigation showed that CG composite with higher graphene composition exhibits higher conductivity. The highest conductivity (2.85×10-4 S cm-1) was observed at 60 wt. % graphene composition. Sample without graphene showed the lowest conductivity of 1.77×10-7 S cm-1, which acts as an insulator. The high conductivity of CG composite can be associated with the X-ray diffraction (XRD) patterns. The XRD patterns of α-cellulose exhibits a decrease in crystallinity at peak 15° and 22° due to the depolymerization in CG composite. At 60 wt. % composition, XRD pattern showed the decrease in intensity at peak 26° indicates that graphene is more dispersed in the cellulose mixture. This is supported by Fourier transform infrared spectrum of CG composite where the absorption peaks of C-O stretching are weakened at wavelength of 1163 and 1032 cm-1, suggested dehydration and rupture of cellulose. The dehydration and rupture of cellulose result in the high conductivity of CG composite. This research is believed to provide an eco-friendly method to produce cellulose/graphene composite which is useful in future applications of energy.