The new complexes [CuL2
(H2
O)2
] and [FeL2
(CH3
O)2
] in which L =
β-mangostin were synthesised and characterised. The structure of the
ligand, β-mangostin was confirmed using NMR and the purity of ligand
was determined using HPLC. Both Cu(II) and Fe(II) complexes were
prepared by reaction between the ligand and the acetate of the metals in
one-step reaction. The synthesised compounds have been characterised
using UV-Visible, FTIR and CHNS analyser. Ligand and metal complexes
were tested against bacteria to assess on their antimicrobial properties using
Minimum Inhibitory Concentrations (MICs) and Minimum Bactericidal
Concentrations (MBCs) method. The elemental analysis and spectra data
suggested octahedral geometry for both Cu(II) and Fe(II) complexes. The
IR spectroscopy revealed that the chelation of Cu2+ and Fe2+ ion occurred
with hydroxyl and carbonyl group at C9
and C1 respectively of β-mangostin.
Both Cu(II) and Fe(II) complexes showed stronger inhibition against
Pseudomonas aeruginosa, Proteus vulgaris, Klebsiella pneumoniae and
Salmonella pneumonia at concentration 900 mg/mL and Escherichia coli
at 450 mg/mL compared to the ligand itself
Heavy metal ions contamination has become more serious which is caused
by the releasing of toxic waterfrom industrial area and landfill that are very
harmful to all living organism especially human and can even cause death
if contaminated in small amount of heavy metal concentration. Currently,
peoples are using classic method namely electrochemical treatment,
chemical oxidation/reduction, chemical precipitation and reverse osmosis
to eliminate the metal ions from toxic water. Unfortunately, these methods
are costly and not environmentally friendly as compared to bioadsorption
method, where agricultural waste is used as biosorbent to remove heavy
metals. Two types of agricultural waste used in this research namely oil
palm mesocarp fiber (Elaesis guineensis sp.) (OPMF) and mangrove bark
(Rhizophora apiculate sp.) (MB) biomass. Through chemical treatment,
the removal efficiency was found to improve. The removal efficiency is
examined based on four specification namely dosage, of biosorbent to
adsorb fourtypes of metalsion explicitly nickel, lead, copper, and chromium.
The research has found that the removal efficiency of MB was lower than
OPMF; whereas, the multiple metals ions removal efficiency decreased in
the order of Pb2+ > Cu2+ > Ni2+ > Cr2+.