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Fulltext Synthesis and adsorption studies for newly prepared Ni2+-imprinted polymer co-functionalized with picolinic acid

Mehamod, F.S., Kadir, M.A., Jusoh, N., Yusof, N.F., Suah, F.B.

ASM Science Journal, 2018;11(101):114-123.
MyJurnal

The development of new adsorbent has rapidly increased in order to overcome the problem
of waste water treatment from heavy metal pollution. The ability of nickel (II)-ion imprinted
polymer (Ni-IIP) as an alternative adsorbent for the removal of nickel ion from aqueous has
been investigated. The Ni-IIP was prepared via bulk polymerization by using functional
monomers; methylacrylic acid (MAA) with picolinic acid as a co-monomer. Nickel ion was
used as template, AIBN as initiator and EGDMA as cross-linking agent. Non-imprinted control
polymer (NIP) was prepared in the same manner as Ni-IIP but in the absence of nickel
ion. The resultant of Ni-IIP and NIP were characterized by using Fourier Transform Infrared
(FTIR) spectroscopy and Scanning Electron Microscope (SEM). Result showed that, the adsorption
of nickel ion onto Ni-IIP increased as the adsorbent dosage increased and contact
time is prolonged. The adsorption isotherm model for Ni-IIP and NIP were fitted well with
Freundlich and Langmuir, respectively. Kinetic study for both Ni-IIP and NIP were followed
the pseudo-second order, indicates that the rate-limiting step is the surface adsorption that
involves chemisorption. Selectivity studies showed that the distribution coefficient of Ni2+
was higher compared to Zn2+, Mg2+ and Pb2+. The present work has successfully synthesized
Ni-IIP particles with good potential in recognition of Ni2+ ions in an aqueous medium.
Fulltext Healthcare providers’ knowledge towards medication use in breastfeeding: an interventional study

Hamat, N.N., Yusof, N.N., Ramli, N.I., Zubir, N.Z., Wahairi, N., Jusoh, N., et al.

JUMMEC, 2019;22(2):39-42.
MyJurnal

Background: Most postpartum women are prescribed at least one medication; so the safety of the medication
is a major concern. In 2017, 11% of 815 questions received by the Pharmacy Drug Information Services at seven
clinics in Dungun is related to medication use in breastfeeding. Thus, this study was carried out to evaluate
the attitudes of healthcare providers (HCPs) and to investigate the effect of knowledge about medication use
in breastfeeding among HCPs; pre- and post-educational intervention.

Methods: An interventional study was carried out among medical officers, assistant medical officers,
pharmacists and pharmacist assistants from seven clinics in the district of Dungun, Malaysia. The questionnaires
were distributed during pre- and post-intervention period. The interventions in this study included continuous
medical education (CME) and the use of a booklet regarding medication use for breastfeeding women. The
data collected were analyzed using Statistical Package for Social Studies (SPSS) and presented as frequencies,
means, and standard deviations.

Results: Fifty HCPs were enrolled in this study and over 20% of them advised mothers to discontinue
breastfeeding whenever they are prescribed any medication. The knowledge of HCPs about medication use in
breastfeeding women was significantly improved (Z= -5.917, p
Fulltext Infant feeding practices and attitudes of mothers in Kelantan towards breastfeeding

Yusof YA, Mazlan M, Ibrahim N, Jusoh NM

Med J Malaysia, 1995 Jun;50(2):150-5.
PMID: 7565185

The incidence of breastfeeding among 96 mothers (88/96 were Malays) who were attending various clinics at Universiti Sains Malaysia Hospital and Kota Bharu General Hospital was about 95%. The feeding patterns show that about 72% of mothers gave mixed feedings (breastmilk plus infant formula) while only 30% gave exclusive breastmilk to their infants in the first six months. Two main reasons for giving mixed feedings were that mothers had to start working soon after giving birth and reported "insufficient milk". Mixed feedings were seen to be more prevalent in the higher income group mothers (> RM1000 per month). About 64% of them who breastfed their child continued to do so beyond 6 months. Regarding their knowledge on breastfeeding, most mothers (98%) knew that breastmilk is good for baby's health, economical, strengthens bonding between mother and child, and was sufficient for the sustenance of the baby. However, when asked about colostrum, 66% of mothers who breastfed their child threw away the colostrum before feeding; some of the reasons given were that colostrum is dirty, and not suitable for the baby's health and it might cause some diseases.
Fulltext Obesity among Health-Care Workers: Which Occupations Are at Higher Risk of Being Obese?

Kunyahamu MS, Daud A, Jusoh N

Int J Environ Res Public Health, 2021 04 20;18(8).
PMID: 33924182 DOI: 10.3390/ijerph18084381

Obesity among health-care workers (HCWs) is an important issue as it can affect both their health condition and their professional capability. Although adult obesity is attributable to occupational factors, few reports are available on Malaysian health-care workers' obesity and whether different health-care job categories are related to workers' obesity. This study aimed to determine the prevalence of obesity among HCWs and the association between various HCW job categories and obesity. A cross-sectional study was conducted by analyzing secondary data from the 2019 annual cardiovascular health screening program, which included information regarding all government health-care workers in the east coast region of Peninsular Malaysia. The subject's body mass index (BMI) was categorized according to WHO criteria. Only 43% of the subjects had a normal BMI, while 33.1% were categorized as overweight, and 21.1% were obese. Different HCWs' job categories were shown to be significantly associated with their obesity status, with nurses apparently having a higher risk of being obese (Adj OR = 1.91, 95% CI 1.45, 2.53, p-value < 0.001). This study's results require further exploration of HCWs' working condition factors and for different job categories that contribute to obesity. Public health intervention programs to combat obesity should be implemented that primarily target HCW groups at the highest risk of obesity.
Fulltext Tailoring CO2/CH4 Separation Performance of Mixed Matrix Membranes by Using ZIF-8 Particles Functionalized with Different Amine Groups

Suhaimi NH, Yeong YF, Ch'ng CWM, Jusoh N

Polymers (Basel), 2019 Dec 09;11(12).
PMID: 31835373 DOI: 10.3390/polym11122042

CO2 separation from CH4 by using mixed matrix membranes has received great attention due to its higher separation performance compared to neat polymeric membrane. However, Robeson's trade-off between permeability and selectivity still remains a major challenge for mixed matrix membrane in CO2/CH4 separation. In this work, we report the preparation, characterization and CO2/CH4 gas separation properties of mixed matrix membranes containing 6FDA-durene polyimide and ZIF-8 particles functionalized with different types of amine groups. The purpose of introducing amino-functional groups into the filler is to improve the interaction between the filler and polymer, thus enhancing the CO2 /CH4 separation properties. ZIF-8 were functionalized with three differents amino-functional group including 3-(Trimethoxysilyl)propylamine (APTMS), N-[3-(Dimethoxymethylsilyl)propyl ethylenediamine (AAPTMS) and N1-(3-Trimethoxysilylpropyl) diethylenetriamine (AEPTMS). The structural and morphology properties of the resultant membranes were characterized by using different analytical tools. Subsequently, the permeability of CO2 and CH4 gases over the resultant membranes were measured. The results showed that the membrane containing 0.5 wt% AAPTMS-functionalized ZIF-8 in 6FDA- durene polymer matrix displayed highest CO2 permeability of 825 Barrer and CO2/CH4 ideal selectivity of 26.2, which successfully lies on Robeson upper bound limit.
Sustainable energy for better social, environmental, and economic returns

Jalil AA, Hamid MYS, Jusoh NWC, Hassan NS

Environ Sci Pollut Res Int, 2023 Nov;30(55):116876-116877.
PMID: 37858029 DOI: 10.1007/s11356-023-30429-4
WITHDRAWN: Sustainable liquid membrane separation using interfacial engineering of deep eutectic solvent and cellulose acetate

Mubashir M, Jusoh N, Majeed Z, Rambabu K, Banat F, Tao Y

J Hazard Mater, 2020 Oct 27.
PMID: 33153798 DOI: 10.1016/j.jhazmat.2020.124345

This article has been withdrawn at the request of the editor. The Publisher apologizes for any inconvenience this may cause. The full Elsevier Policy on Article Withdrawal can be found at https://www.elsevier.com/about/our-business/policies/article-withdrawal.
Interaction between copper and carbon nanotubes triggers their mutual role in the enhanced photodegradation of p-chloroaniline

Khusnun NF, Jalil AA, Triwahyono S, Jusoh NW, Johari A, Kidam K

Phys Chem Chem Phys, 2016 04 28;18(17):12323-31.
PMID: 27088140 DOI: 10.1039/c5cp08068a

Copper (Cu, 1-5 wt%) was loaded onto carbon nanotubes (CNTs) by a simple electrochemical method. The physicochemical properties of catalysts (Cu/CNTs) were characterized by using X-ray diffraction (XRD), transmission electron microscopy (TEM), nitrogen (N2) adsorption-desorption, Fourier transform infra-red spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and electron spinning resonance (ESR). The results showed that the Cu was distributed well on the CNT surface by the interaction of Cu(2+) ions with -OH and -COOH groups on the CNT surface, which preferentially occurred at the defect sites along the CNT backbone. The Cu-O-C bonds formed were found to play an important role in enhancing the photoactivity of the catalysts. The highest number of Cu-O-C bonds possessed by 3 wt% Cu/CNTs demonstrated the best performance in the degradation of p-chloroaniline (96%) under UV light irradiation within 5 h of reaction at 27 °C and under neutral pH conditions. Kinetic studies showed that the degradation followed the pseudo-first order model and the surface reaction was the controlling step. It is believed that these results could contribute to the synthesis of various supported catalysts for various applications.
Timing of The First Zygotic Cleavage Affects Post-Vitrification Viability of Murine Embryos Produced In Vivo

Jusof WH, Khan NA, Rajikin MH, Satar NA, Mustafa MF, Jusoh N, et al.

Int J Fertil Steril, 2015 07 27;9(2):221-9.
PMID: 26246881

BACKGROUND: Timing of the first zygotic cleavage is an accurate predictor of embryo quality. Embryos that cleaved early (EC) have been shown to exhibit higher develop- mental viability compared to those that cleaved at a later period (LC). However, the vi- ability of EC embryos in comparison to LC embryos after vitrification is unknown. The present study aims to investigate the post-vitrification developmental viability of murine EC versus LC embryos.
MATERIALS AND METHODS: In this experimental study, female ICR mice (6-8 weeks old) were superovulated and cohabited with fertile males for 24 hours. Afterwards, their ovi- ducts were excised and embryos harvested. Embryos at the 2-cell stage were catego- rized as EC embryos, while zygotes with two pronuclei were categorized as LC embryos. Embryos were cultured in M16 medium supplemented with 3% bovine serum albumin (BSA) in a humidified 5% CO2atmosphere. Control embryos were cultured until the blastocyst stage without vitrification. Experimental embryos at the 2-cell stage were vitri- fied for one hour using 40% v/v ethylene glycol, 18% w/v Ficoll-70 and 0.5 M sucrose as the cryoprotectant. We recorded the numbers of surviving embryos from the control and experimental groups and their development until the blastocyst stage. Results were analyzed using the chi-square test.
RESULTS: A significantly higher proportion of EC embryos (96.7%) from the control group developed to the blastocyst stage compared with LC embryos (57.5%, P<0.0001). Similarly, in the experimental group, a significantly higher percentage of vitrified EC embryos (69.4%) reached the blastocyst stage compared to vitrified LC embryos (27.1%, P<0.0001).
CONCLUSION: Vitrified EC embryos are more vitrification tolerant than LC embryos. Prese- lection of EC embryos may be used as a tool for selection of embryos that exhibit higher developmental competence after vitrification.
Supported liquid membrane extraction of nickel using stable composite SPEEK/PVDF support impregnated with a sustainable liquid membrane

Sulaiman RNR, Jusoh N, Othman N, Noah NFM, Rosly MB, Rahman HA

J Hazard Mater, 2019 12 15;380:120895.
PMID: 31351388 DOI: 10.1016/j.jhazmat.2019.120895

A sustainable and stable supported liquid membrane (SLM) extraction of nickel was developed via impregnation of sustainable liquid membrane in the composite membrane support consisting of polyvinylidene fluoride (PVDF) and sulfonated poly (ether ether ketone) (SPEEK). Bis-2-ethylhexyl phosphate (D2EHPA), 1-octanol, refined palm oil and sulfuric acid were employed as extractant, synergist extractant, diluent and strippant, respectively. Variables studied including effect of refined palm oil compositions as well as the configurations and thicknesses of SPEEK. Lifespan of SLM was evaluated by recycling the composite membrane support. Results revealed that upon using 100% refined palm oil, about 100% of nickel was extracted and recovered in 10 and 14 h, respectively. Composite SPEEK/PVDF stabilized SLM by reducing liquid membrane loss from 47 to 23% upon applying SPEEK at the feed side of PVDF support. High permeability and flux values were obtained at 9.26 x 10-4 cms-1 and 6.48 x 10-7 molcm-2s-1 when increasing SPEEK thickness from 0.025 to 0.055 mm, respectively. The lifespan of SLM was extended up to ninth cycles with low weight loss percentage of the impregnated composite membrane (8%). In conclusion, the SPEEK/PVDF impregnated with refined palm oil has improved the stability of SLM extraction of nickel ions from industrial wastewater.
Fulltext 3D Microfluidic Bone Tumor Microenvironment Comprised of Hydroxyapatite/Fibrin Composite

Ahn J, Lim J, Jusoh N, Lee J, Park TE, Kim Y, et al.

Front Bioeng Biotechnol, 2019;7:168.
PMID: 31380359 DOI: 10.3389/fbioe.2019.00168

Bone is one of the most common sites of cancer metastasis, as its fertile microenvironment attracts tumor cells. The unique mechanical properties of bone extracellular matrix (ECM), mainly composed of hydroxyapatite (HA) affect a number of cellular responses in the tumor microenvironment (TME) such as proliferation, migration, viability, and morphology, as well as angiogenic activity, which is related to bone metastasis. In this study, we engineered a bone-mimetic microenvironment to investigate the interactions between the TME and HA using a microfluidic platform designed for culturing tumor cells in 3D bone-mimetic composite of HA and fibrin. We developed a bone metastasis TME model from colorectal cancer (SW620) and gastric cancer (MKN74) cells, which has very poor prognosis but rarely been investigated. The microfluidic platform enabled straightforward formation of 3D TME composed the hydrogel and multiple cell types. This facilitated monitoring of the effect of HA concentration and culture time on the TME. In 3D bone mimicking culture, we found that HA rich microenvironment affects cell viability, proliferation and cancer cell cytoplasmic volume in a manner dependent on the different metastatic cancer cell types and culture duration indicating the spatial heterogeneity (different origin of metastatic cancer) and temporal heterogeneity (growth time of cancer) of TME. We also found that both SW620 and MKN72 cells exhibited significantly reduced migration at higher HA concentration in our platform indicating inhibitory effect of HA in both cancer cells migration. Next, we quantitatively analyzed angiogenic sprouts induced by paracrine factors that secreted by TME and showed paracrine signals from tumor and stromal cell with a high HA concentration resulted in the formation of fewer sprouts. Finally we reconstituted vascularized TME allowing direct interaction between angiogenic sprouts and tumor-stroma microspheroids in a bone-mimicking microenvironment composing a tunable HA/fibrin composite. Our multifarious approach could be applied to drug screening and mechanistic studies of the metastasis, growth, and progression of bone tumors.
Fulltext Brachytherapy of tongue carcinoma in a patient with difficult airway: anesthetic considerations

Ghaffar ZA, Chong SE, Tan KL, Appalanaido GK, Musa MY, Hussin HB, et al.

J Contemp Brachytherapy, 2018 Dec;10(6):573-576.
PMID: 30662482 DOI: 10.5114/jcb.2018.79856

The practice of brachytherapy in unresectable tongue carcinoma is gaining popularity. However, this procedure poses specific anesthetic challenges, particularly challenges of airway sharing and a higher rate of difficult airway. We report a 74-year-old chronic smoker, chronic alcoholic with history of stroke, who had undergone brachytherapy for tongue carcinoma. Apart from a huge tongue tumor, he had an epiglottic mass but refused elective tracheostomy. This had led to a few critical states throughout the process of treatment, including a metabolic crisis due to thiamine deficiency and difficult airway crisis. To our best knowledge, there have been no reported case on a patient with vocal cord mass undergoing tongue brachytherapy. We hope sharing of this experience may aid the management of similar patients in future.
Fulltext CD80 Insights as Therapeutic Target in the Current and Future Treatment Options of Frequent-Relapse Minimal Change Disease

Teh YM, Lim SK, Jusoh N, Osman K, Mualif SA

Biomed Res Int, 2021;2021:6671552.
PMID: 33506028 DOI: 10.1155/2021/6671552

Minimal change disease (MCD) is the most common cause of idiopathic nephrotic syndrome in children, and it is well known for its multifactorial causes which are the manifestation of the disease. Proteinuria is an early consequence of podocyte injury and a typical sign of kidney disease. Steroid-sensitive patients react well with glucocorticoids, but there is a high chance of multiple relapses. CD80, also known as B7-1, is generally expressed on antigen-presenting cells (APCs) in steroid-sensitive MCD patients. Various glomerular disease models associated with proteinuria demonstrated that the detection of CD80 with the increase of urinary CD80 was strongly associated closely with frequent-relapse MCD patients. The role of CD80 in MCD became controversial because one contradicts finding. This review covers the treatment alternatives for MCD with the insight of CD80 as a potential therapeutic target. The promising effectiveness of CD20 (rituximab) antibody and CD80 inhibitor (abatacept) encourages further investigation of CD80 as a therapeutic target in frequent-relapse MCD patients. Therapeutic-based antibody towards CD80 (galiximab) had never been investigated in MCD or any kidney-related disease; hence, the role of CD80 is still undetermined. A new therapeutic approach towards MCD is essential to provide broader effective treatment options besides the general immunosuppressive agents with gruesome adverse effects.
Cellulose acetate-based membranes by interfacial engineering and integration of ZIF-62 glass nanoparticles for CO2 separation

Mubashir M, Dumée LF, Fong YY, Jusoh N, Lukose J, Chai WS, et al.

J Hazard Mater, 2021 08 05;415:125639.
PMID: 33740720 DOI: 10.1016/j.jhazmat.2021.125639

Composite membranes typically used for gas separation are susceptible to interfacial voids and CO2 plasticization which adversely affects the gas permeation performance. This paper evaluates routes towards the enhancement of CO2 permeation performance and CO2 plasticization resistance of composite membranes using non-stoichiometric ZIF-62 MOF glass and cellulose acetate (CA). Single and mixed gas permeation results, obtained with CO2 and CH4, demonstrate that the presence of ZIF-62 glass in CA polymer enhanced the CO2 permeability and CO2/CH4 ideal selectivity from 15.8 to 84.8 Barrer and 12.2-35.3, respectively. The composite membrane loaded with 8 wt% of ZIF-62 glass showed the highest CO2 permeability and CO2/CH4 ideal selectivity of 84.8 Barrer and 35.3, which were 436.7% and 189.3% higher compared to the pristine CA membrane, respectively. A CO2 plasticization pressure of 26 bar was achieved for the composite membranes, which is 160% higher compared to the pristine CA membranes, at about 10 bar. The mechanisms for the materials stabilization and greater separation performance were attributed to higher pore size (7.3 Å) and significant CO2 adsorption on the unsaturated metal nodes followed by metal cites electrostatic interaction with CO2. These findings confirm the potential of ZIF-62 glass materials as promising materials solutions towards the design of composite membranes for CO2 separation at industrial scale.
Emulsion liquid membrane modeling for chromium removal from electroplating wastewater using TOMAC as a carrier

Othman N, Noah NFM, Sulaiman RNR, Jusoh N, Tan WT

Water Environ Res, 2021 Sep;93(9):1669-1679.
PMID: 33704848 DOI: 10.1002/wer.1551

Hexavalent chromium, emanating primarily from the electroplating industries, can be reduced to the less toxic trivalent variety by several methods, including emulsion liquid membrane (ELM). In this work, studies on the continuous removal of chromium from authentic electroplating wastewater by ELM are reported. The effects of treat ratio, external feed phase, and stripping agent concentration were examined. A mathematical boundary breakage model was used to study the extraction efficiency of chromium through the ELM process. The model representing the prediction of ELM extraction performance for chromium was validated through the comparison between the simulation and experimental results. The result showed the simulation model is found to be in good agreement with the experimental result. Almost 100% of 40 ppm chromium in the external feed phase was extracted within 3 to 5 min using 0.022 M TOMAC as extractant, 1.0 M acidic thiourea in the internal phase, and 1 to 5 of treat ratio. PRACTITIONER POINTS: Hexavalent chromium, emanating primarily from electroplating industries, can be reduced to the less toxic trivalent using ELM process. The developed method was tested for its applicability with predominant species of Cr2 O7 2- in real rinse electroplating wastewater. The extraction efficiency (%) of Cr (VI) was almost 100% for 40 ppm Cr in the external feed phase within 3 to 5 min. The result showed the simulation model is found to be in good agreement with the experimental result.
Rapid-synthesis of zeolite T via sonochemical-assisted hydrothermal growth method

Jusoh N, Yeong YF, Mohamad M, Lau KK, M Shariff A

Ultrason Sonochem, 2017 01;34:273-280.
PMID: 27773246 DOI: 10.1016/j.ultsonch.2016.05.033

Sonochemical-assisted method has been identified as one of the potential pre-treatment methods which could reduce the formation duration of zeolite as well as other microporous and mesoporous materials. In the present work, zeolite T was synthesized via sonochemical-assisted pre-treatment prior to hydrothermal growth. The durations for sonochemical-assisted pre-treatment were varied from 30min to 90min. Meanwhile, the hydrothermal growth durations were ranged from 0.5 to 3days. The physicochemical properties of the resulting samples were characterized using XRD, FESEM, FTIR and BET. As verified by XRD, the samples synthesized via hydrothermal growth durations of 1, 2 and 3days and sonochemical-assisted pre-treatment durations of 60min and 90min demonstrated zeolite T structure. The samples which underwent sonochemical-assisted pre-treatment duration of 60min yielded higher crystallinity with negligible change of zeolite T morphology. Overall, the lengthy synthesis duration of zeolite T has been successfully reduced from 7days to 1day by applying sonochemical-assisted pre-treatment of 60min, while synthesis duration of 0.5days via sonochemical-assisted pre-treatment of 60min was not sufficient to produce zeolite T structure.
Fulltext Effect of a Different Number of Amine-Functional Groups on the Gas Sorption and Permeation Behavior of a Hybrid Membrane Comprising of Impregnated Linde T and 4,4'- (Hexafluoroisopropylidene) Diphthalic Anhydride-Derived Polyimide

Jusoh N, Yeong YF, Lock SSM, Yub Harun N, Mohd Yusoff MH

Polymers (Basel), 2019 Nov 04;11(11).
PMID: 31689895 DOI: 10.3390/polym11111807

The bottleneck of conventional polymeric membranes applied in industry has a tradeoff between permeability and selectivity that deters its widespread expansion. This can be circumvented through a hybrid membrane that utilizes the advantages of inorganic and polymer materials to improve the gas separation performance. The approach can be further enhanced through the incorporation of amine-impregnated fillers that has the potential to minimize defects while simultaneously enhancing gas affinity. An innovative combination between impregnated Linde T with different numbers of amine-functional groups (i.e., monoamine, diamine, and triamine) and 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA)-derived polyimide has been elucidated to explore its potential in CO2/CH4 separation. Detailed physical properties (i.e., free volume and glass transition temperature) and gas transport behavior (i.e., solubility, permeability, and diffusivity) of the fabricated membranes have been examined to unveil the effect of different numbers of amine-functional groups in Linde T fillers. It was found that a hybrid membrane impregnated with Linde T using a diamine functional group demonstrated the highest improvement compared to a pristine polyimide with 3.75- and 1.75-fold enhancements in CO2/CH4 selectivities and CO2 permeability, respectively, which successfully lies on the 2008 Robeson's upper bound. The novel coupling of diamine-impregnated Linde T and 6FDA-derived polyimide is a promising candidate for application in large-scale CO2 removal processes.
A review on synergistic coexisting pollutants for efficient photocatalytic reaction in wastewater remediation

Aziz FFA, Jalil AA, Hassan NS, Fauzi AA, Azami MS, Jusoh NWC, et al.

Environ Res, 2022 Jan 29;209:112748.
PMID: 35101397 DOI: 10.1016/j.envres.2022.112748

With the tremendous development of the economy and industry, the pollution of water is becoming more serious due to the excessive chemical wastes that need to remove thru reduction or oxidation reactions. Simultaneous removal of dual pollutants via photocatalytic redox reaction has been tremendously explored in the last five years due to effective decontamination of pollutants compared to a single pollutants system. In a photocatalysis mechanism, the holes in the valence band can remarkably promote the oxidation of a pollutant. At the same time, photoexcited electrons are also consumed for the reduction reaction. The synergistic between the reduction and oxidation inhibits the recombination of electron-hole pairs extending their lifetime. In this review, the binary pollutants that selectively removed via photocatalysis reduction or oxidation are classified according to heavy metal-organic pollutant (HM/OP), heavy metal-heavy metal (HM/HM) and organic-organic pollutants (OP/OP). The intrinsic between the pollutants was explained in three different mechanisms including inhibition of electron-hole recombination, ligand to metal charge transfer and electrostatic attraction. Several strategies for the enhancement of this treatment method which are designation of catalysts, pH of mixed pollutants and addition of additive were discussed. This review offers a recent perspective on the development of photocatalysis system for industrial applications.
A molecular simulation study on amine-functionalized silica/polysulfone mixed matrix membrane for mixed gas separation

Asif K, Lock SSM, Taqvi SAA, Jusoh N, Yiin CL, Chin BLF

Chemosphere, 2023 Jan;311(Pt 1):136936.
PMID: 36273613 DOI: 10.1016/j.chemosphere.2022.136936

Polysulfone (PSF) based mixed matrix membranes (MMMs) are one of the most broadly studied polymeric materials used for CO2/CH4 separation. The performance of existing PSF membranes encounters a bottleneck for widespread expansion in industrial applications due to the trade-off amongst permeability and selectivity. Membrane performance has been postulated to be enhanced via functionalization of filler at different weight percentages. Nonetheless, the preparation of functionalized MMMs without defects and its empirical study that exhibits improved CO2/CH4 separation performance is challenging at an experimental scale that needs prior knowledge of the compatibility between the filler and polymer. Molecular simulation approaches can be used to explore the effect of functionalization on MMM's gas transport properties at an atomic level without the challenges in the experimental study, however, they have received less scrutiny to date. In addition, most of the research has focused on pure gas studies while mixed gas transport properties that reflect real separation in functionalized silica/PSF MMMs are scarcely available. In this work, a molecular simulation computational framework has been developed to investigate the structural, physical properties and gas transport behavior of amine-functionalized silica/PSF-based MMMs. The effect of varying weight percentages (i.e., 15-30 wt.%) of amine-functionalized silica and gas concentrations (i.e., 30% CH4/CO2, 50% CH4/CO2, and 70% CH4/CO2) on physical and gas transport characteristics in amine-functionalized silica/PSF MMMs at 308.15 K and 1 atm has been investigated. Functionalization of silica nanoparticles was found to increase the diffusion and solubility coefficients, leading to an increase in the percentage enhancement of permeability and selectivity for amine-functionalized silica/PSF MMM by 566% and 56%, respectively, compared to silica/PSF-based MMMs at optimal weight percentage of 20 wt.%. The model's permeability differed by 7.1% under mixed gas conditions. The findings of this study could help to improve real CO2/CH4 separation in the future design and concept of functionalized MMMs using molecular simulation and empirical modeling strategies.
Simultaneous extraction and enrichment of reactive dye using green emulsion liquid membrane system

Othman N, Raja Sulaiman RN, Rahman HA, Noah NFM, Jusoh N, Idroas M

Environ Technol, 2019 Apr;40(11):1476-1484.
PMID: 29300678 DOI: 10.1080/09593330.2018.1424258

Currently, an extractive green palm oil-based emulsion liquid membrane (ELM) has been used for simultaneous extraction and enrichment of Reactive Red 3BS from simulated synthetic dye wastewater. The ELM consists of two main phases, which are organic liquid membrane (LM) and stripping solution. During the extraction process, the ELM was dispersed into the simulated synthetic dye wastewater containing the Reactive Red 3BS complexes. The organic LM contains tridodecylamine (TDA), Sorbitan Monooleate (Span 80) and palm oil as a carrier, surfactant and diluent, respectively. The sodium bicarbonate (NaHCO3) was used as stripping solution for the enrichment process. Several important parameters that affected the simultaneous extraction and enrichment of Reactive Red 3BS, such as carrier and stripping agent concentrations, extraction time and treat ratio, were investigated. The results showed that almost 90% of Reactive Red 3BS ions were successfully extracted with 10 times enrichment in the stripping phase at the optimum conditions of 0.2 M TDA, 0.1 M NaHCO3, 5 min of extraction time and 1:5 of treat ratio. Hence, it can be concluded that palm oil possesses a high potential as green diluent in future technology, especially in ELM process for the removal and recovery of Reactive Red 3BS from synthetic dye wastewater.

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