Displaying publications 61 - 80 of 125 in total

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  1. Abdollahi Y, Sabbaghi S, Abouzari-Lotf E, Jahangirian H, Sairi NA
    Water Sci Technol, 2018 Mar;77(5-6):1493-1504.
    PMID: 29595152 DOI: 10.2166/wst.2018.017
    The global attention has been focused on degradation of the environmental organic pollutants through green methods such as advanced oxidation processes (AOPs) under sunlight. However, AOPs have not yet been efficient in function of the photocatalyst that has been used. In this work, firstly, CaCu3Ti4O12 nanocomposite was simultaneously synthesized and decorated in different amounts of graphene oxide to enhance photodegradation of the organics. The result of the photocatalyst characterization showed that the sample with 8% graphene presented optimum photo-electrical properties such as low band gap energy and a great surface area. Secondly, the photocatalyst was applied for photodegradation of an organic model in a batch photoreactor. Thirdly, to scale up the process and optimize the efficiency, the photodegradation was modeled by multivariate semi-empirical methods. As the optimized condition showed, 45 mg/L of the methyl-orange has been removed at pH 5.8 by 0.96 g/L of the photocatalyst during 288 min of the light irradiation. Moreover, the photodegradation has been scaled up for industrial applications by determining the importance of the input effective variables according to the following organics order > photocatalyst > pH > irradiation time.
    Matched MeSH terms: Sunlight*
  2. Hak CH, Sim LC, Leong KH, Lim PF, Chin YH, Saravanan P
    Environ Sci Pollut Res Int, 2018 Sep;25(25):25401-25412.
    PMID: 29951757 DOI: 10.1007/s11356-018-2632-8
    In this work, natural sunlight successfully induced the deposition of gold (Au), silver (Ag), and palladium (Pd) nanoparticles (NPs) with 17.10, 9.07, and 12.70 wt% onto the surface of graphitic carbon nitride (g-C3N4). The photocatalytic evaluation was carried out by adopting Bisphenol A (BPA) as a pollutant under natural sunlight irradiation. The presence of noble metals was confirmed by EDX, HRTEM, and XPS analysis. The deposition of Ag NPs (7.9 nm) resulted in the degradation rate which was 2.15-fold higher than pure g-C3N4 due to its relatively small particle size, contributing to superior charge separation efficiency. Au/g-C3N4 unveiled inferior photoactivity because the LSPR phenomenon provided two pathways for electron transfer between Au NPs and g-C3N4 further diminished the performance. The improved degradation lies crucially on the particle size and Schottky barrier formation at the interface of M/g-C3N4 (M=Au, Ag, and Pd) but not the visible light harvesting properties. The mechanism insight revealed the holes (h+) and superoxide radical (•O2-) radical actively involved in photocatalytic reaction for all composites.
    Matched MeSH terms: Sunlight*
  3. Yeang HY
    Ann Bot, 2015 Jul;116(1):15-22.
    PMID: 26070640 DOI: 10.1093/aob/mcv070
    BACKGROUND AND AIMS: An endogenous rhythm synchronized to dawn cannot time photosynthesis-linked genes to peak consistently at noon since the interval between sunrise and noon changes seasonally. In this study, a solar clock model that circumvents this limitation is proposed using two daily timing references synchronized to noon and midnight. Other rhythmic genes that are not directly linked to photosynthesis, and which peak at other times, also find an adaptive advantage in entrainment to the solar rhythm.

    METHODS: Fourteen datasets extracted from three published papers were used in a meta-analysis to examine the cyclic behaviour of the Arabidopsis thaliana photosynthesis-related gene CAB2 and the clock oscillator genes TOC1 and LHY in T cycles and N-H cycles.

    KEY RESULTS: Changes in the rhythms of CAB2, TOC1 and LHY in plants subjected to non-24-h light:dark cycles matched the hypothesized changes in their behaviour as predicted by the solar clock model, thus validating it. The analysis further showed that TOC1 expression peaked ∼5·5 h after mid-day, CAB2 peaked close to noon, while LHY peaked ∼7·5 h after midnight, regardless of the cycle period, the photoperiod or the light:dark period ratio. The solar clock model correctly predicted the zeitgeber timing of these genes under 11 different lighting regimes comprising combinations of seven light periods, nine dark periods, four cycle periods and four light:dark period ratios. In short cycles that terminated before LHY could be expressed, the solar clock correctly predicted zeitgeber timing of its expression in the following cycle.

    CONCLUSIONS: Regulation of gene phases by the solar clock enables the plant to tell the time, by which means a large number of genes are regulated. This facilitates the initiation of gene expression even before the arrival of sunrise, sunset or noon, thus allowing the plant to 'anticipate' dawn, dusk or mid-day respectively, independently of the photoperiod.

    Matched MeSH terms: Sunlight*
  4. Basri DF, Abu Bakar NF, Fudholi A, Ruslan MH, Saroeun I
    J Environ Public Health, 2015;2015:470968.
    PMID: 25688274 DOI: 10.1155/2015/470968
    The content of 12 elements in Cambodian dried striped snakehead fish was determined using inductively coupled plasma mass spectrometry. The present study compares the level of the trace toxic metals and nutritional trace elements in the fish processed using solar drying system (SDS) and open sun drying (OSD). The skin of SDS fish has lower level of As, Pb, and Cd compared to the OSD sample. As such, the flesh of the fish accumulated higher amount of toxic metals during OSD compared to SDS. However, arsenic was detected in both samples within the safe limit. The nutritional elements (Fe, Mn, Mg, Se, Mo, Cu, Ni, and Cr) were higher in the skin sample SDS fish compared to OSD fish. These beneficial metals were not accumulated in the flesh sample SDS fish demonstrating lower level compared to drying under conventional system. The reddish coloration of the SDS fish was due to the presence of high Cu content in both the skin and flesh samples which possibly account for no mold formation 5 days after packaging. As conclusion, drying of Cambodian C. striata using solar-assisted system has proven higher content of the nutritious elements compared to using the conventional system despite only slight difference in the toxic metals level between the two systems.
    Matched MeSH terms: Sunlight
  5. Ikhsan NI, Rameshkumar P, Pandikumar A, Mehmood Shahid M, Huang NM, Vijay Kumar S, et al.
    Talanta, 2015 Nov 1;144:908-14.
    PMID: 26452907 DOI: 10.1016/j.talanta.2015.07.050
    In this report, silver nanoparticles (Ag NPs) were successfully deposited on graphene oxide (GO) sheets to form GO-Ag nanocomposite using garlic extract and sunlight and the nanocomposite modified glassy carbon (GC) electrode was applied as an electrochemical sensor for the detection of nitrite ions. The formation of GO-Ag nanocomposite was confirmed by using UV-visible absorption spectroscopy, TEM, XRD and FTIR spectroscopy analyses. Further, TEM pictures showed a uniform distribution Ag on GO sheets with an average size of 19 nm. The nanocomposite modified electrode produced synergistic catalytic current in nitrite oxidation with a negative shift in overpotential. The limit of detection (LOD) values were found as 2.1 µM and 37 nM, respectively using linear sweep voltammetry (LSV) and amperometric i-t curve techniques. The proposed sensor was stable, reproducible, sensitive and selective toward the detection nitrite and could be applied for the detection of nitrite in real water sample.
    Matched MeSH terms: Sunlight
  6. Rad S, Shamsudin S, Taha MR, Shahid S
    Water Sci Technol, 2016;73(2):405-13.
    PMID: 26819397 DOI: 10.2166/wst.2015.465
    The photo-degradation of nutrients in stormwater in photocatalytic reactor wet detention pond using nano titanium dioxide (TiO2) in concrete was investigated in a scale model as a new stormwater treatment method. Degradation of phosphate and nitrate in the presence of nano-TiO2 under natural ultra violet (UV) from tropical sunlight was monitored for 3 weeks compared with normal ponds. Two types of cement, including ordinary Portland and white cement mixed with TiO2 nano powder, were used as a thin cover to surround the body of the pond. Experiments with and without the catalyst were carried out for comparison and control. Average Anatase diameter of 25 nm and Rutile 100 nm nano particles were applied at three different mixtures of 3, 10 and 30% weight. The amounts of algae available orthophosphate and nitrate, which cause eutrophication in the ponds, were measured during the tests. Results revealed that the utilization of 3% up to 30% weight nano-TiO2 can improve stormwater outflow quality by up to 25% after 48 h and 57% after 3 weeks compared with the control sample in normal conditions with average nutrient (phosphate and nitrate) removal of 4% after 48 h and 10% after 3 weeks.
    Matched MeSH terms: Sunlight
  7. Marshall DJ, Rezende EL, Baharuddin N, Choi F, Helmuth B
    Ecol Evol, 2015 12;5(24):5905-19.
    PMID: 26811764 DOI: 10.1002/ece3.1785
    Tropical ectotherms are predicted to be especially vulnerable to climate change because their thermal tolerance limits generally lie close to current maximum air temperatures. This prediction derives primarily from studies on insects and lizards and remains untested for other taxa with contrasting ecologies. We studied the HCT (heat coma temperatures) and ULT (upper lethal temperatures) of 40 species of tropical eulittoral snails (Littorinidae and Neritidae) inhabiting exposed rocky shores and shaded mangrove forests in Oceania, Africa, Asia and North America. We also estimated extremes in animal body temperature at each site using a simple heat budget model and historical (20 years) air temperature and solar radiation data. Phylogenetic analyses suggest that HCT and ULT exhibit limited adaptive variation across habitats (mangroves vs. rocky shores) or geographic locations despite their contrasting thermal regimes. Instead, the elevated heat tolerance of these species (HCT = 44.5 ± 1.8°C and ULT = 52.1 ± 2.2°C) seems to reflect the extreme temperature variability of intertidal systems. Sensitivity to climate warming, which was quantified as the difference between HCT or ULT and maximum body temperature, differed greatly between snails from sunny (rocky shore; Thermal Safety Margin, TSM = -14.8 ± 3.3°C and -6.2 ± 4.4°C for HCT and ULT, respectively) and shaded (mangrove) habitats (TSM = 5.1 ± 3.6°C and 12.5 ± 3.6°C). Negative TSMs in rocky shore animals suggest that mortality is likely ameliorated during extreme climatic events by behavioral thermoregulation. Given the low variability in heat tolerance across species, habitat and geographic location account for most of the variation in TSM and may adequately predict the vulnerability to climate change. These findings caution against generalizations on the impact of global warming across ectothermic taxa and highlight how the consideration of nonmodel animals, ecological transitions, and behavioral responses may alter predictions of studies that ignore these biological details.
    Matched MeSH terms: Sunlight
  8. Chang KH, Yew CH, Abdullah AF
    J Forensic Sci, 2015 Jul;60(4):869-77.
    PMID: 25771708 DOI: 10.1111/1556-4029.12745
    Gunshot residues, produced after shooting activity, have acquired their importance in analysis due to the notoriety of firearms-related crimes. In this study, solid-phase microextraction was performed to extract the headspace composition of spent cartridges using 85-μm polyacrylate fiber at 66°C for 21 min. Organic compounds, that is, naphthalene, 2,6-dinitrotoluene, 2,4-dinitrotoluene, diphenylamine, and dibutyl phthalate were detected and analyzed by gas chromatography-flame ionization detection technique. Evaluation of chromatograms for diphenylamine, dibutyl phthalate, and naphthalene indicates the period after a gunshot was discharged, whether it was 1 days, 2-4 days, <5 days, 10 days, 20 days, or more than 30 days ago. This study revealed the potential effects of environmental factors such as occasional wind blow and direct sunlight on the estimation of time after spent cartridges were discharged. In conclusion, we proposed reliable alternative in analyzing the headspace composition of spent cartridges in a simulated crime scene.
    Matched MeSH terms: Sunlight
  9. Keith SA, Maynard JA, Edwards AJ, Guest JR, Bauman AG, van Hooidonk R, et al.
    Proc Biol Sci, 2016 05 11;283(1830).
    PMID: 27170709 DOI: 10.1098/rspb.2016.0011
    Coral spawning times have been linked to multiple environmental factors; however, to what extent these factors act as generalized cues across multiple species and large spatial scales is unknown. We used a unique dataset of coral spawning from 34 reefs in the Indian and Pacific Oceans to test if month of spawning and peak spawning month in assemblages of Acropora spp. can be predicted by sea surface temperature (SST), photosynthetically available radiation, wind speed, current speed, rainfall or sunset time. Contrary to the classic view that high mean SST initiates coral spawning, we found rapid increases in SST to be the best predictor in both cases (month of spawning: R(2) = 0.73, peak: R(2) = 0.62). Our findings suggest that a rapid increase in SST provides the dominant proximate cue for coral mass spawning over large geographical scales. We hypothesize that coral spawning is ultimately timed to ensure optimal fertilization success.
    Matched MeSH terms: Sunlight
  10. Naderipour A, Abdul-Malek Z, Ahmad NA, Kamyab H, Ashokkumar V, Ngamcharussrivichai C, et al.
    Environ Technol Innov, 2020 Nov;20:101151.
    PMID: 32923529 DOI: 10.1016/j.eti.2020.101151
    Coronavirus 2019 (COVID-19) has globally affected the human mortality rate and economic history of the modern world. According to the World Health Organization, COVID-19 has caused a severe threat to the health of the vulnerable groups, notably the elderly. There is still some disagreements regarding the source of the virus and its intermediate host. However, the spread of this disease has caused most countries to enforce strict curfew laws and close most industrial and recreational centres. This study aims to show the potential positive effects of COVID-19 on the environment and the increase of renewable energy generation in Malaysia. To prevent the spread of this disease, Malaysia enacted the Movement Control Order (MCO) law in March 2020. Implementation of this law led to a reduction in environmental pollution, especially air pollution, in this country. The greenhouse gases (GHG) emission , which was 8 Mt CO2 eq. from January 2020 to March 2020, reduced to <1 Mt CO2 eq. for April and May. The reduction of GHG emission and pollutant gases allowed more sunlight to reach photovoltaic panels, hence increasing the renewable energy generation.
    Matched MeSH terms: Sunlight
  11. Azmi SZ, Latif MT, Ismail AS, Juneng L, Jemain AA
    Air Qual Atmos Health, 2010 Mar;3(1):53-64.
    PMID: 20376168
    Over the last decades, the development of the Klang Valley (Malaysia), as an urban commercial and industrial area, has elevated the risk of atmospheric pollutions. There are several significant sources of air pollutants which vary depending on the background of the location they originate from. The aim of this study is to determine the trend and status of air quality and their correlation with the meteorological factors at different air quality monitoring stations in the Klang Valley. The data of five major air pollutants (PM(10), CO, SO(2), O(3), NO(2)) were recorded at the Alam Sekitar Sdn Bhd (ASMA) monitoring stations in the Klang Valley, namely Petaling Jaya (S1), Shah Alam (S2) and Gombak (S3). The data from these three stations were compared with the data recorded at Jerantut, Pahang (B), a background station established by the Malaysian Department of Environment. Results show that the concentrations of CO, NO(2) and SO(2) are higher at Petaling Jaya (S1) which is due to influence of heavy traffic. The concentrations of PM(10) and O(3,) however, are predominantly related to regional tropical factors, such as the influence of biomass burning and of ultra violet radiation from sunlight. They can, though, also be influenced by local sources. There are relatively stronger inter-pollutant correlations at the stations of Gombak and Shah Alam, and the results also suggest that heavy traffic flow induces high concentrations of PM(10), CO, NO(2) and SO(2) at the three sampling stations. Additionally, meteorological factors, particularly the ambient temperature and wind speed, may influence the concentration of PM(10) in the atmosphere.
    Matched MeSH terms: Sunlight
  12. Das L, Habib K, Saidur R, Aslfattahi N, Yahya SM, Rubbi F
    Nanomaterials (Basel), 2020 Jul 14;10(7).
    PMID: 32674465 DOI: 10.3390/nano10071372
    In recent years, solar energy technologies have developed an emerging edge. The incessant research to develop a power source alternative to fossil fuel because of its scarcity and detrimental effects on the environment is the main driving force. In addition, nanofluids have gained immense interest as superior heat transfer fluid in solar technologies for the last decades. In this research, a binary solution of ionic liquid (IL) + water based ionanofluids is formulated successfully with two dimensional MXene (Ti3C2) nano additives at three distinct concentrations of 0.05, 0.10, and 0.20 wt % and the optimum concentration is used to check the performance of a hybrid solar PV/T system. The layered structure of MXene and high absorbance of prepared nanofluids have been perceived by SEM and UV-vis respectively. Rheometer and DSC are used to assess the viscosity and heat capacity respectively while transient hot wire technique is engaged for thermal conductivity measurement. A maximum improvement of 47% in thermal conductivity is observed for 0.20 wt % loading of MXene. Furthermore, the viscosity is found to rise insignificantly with addition of Ti3C2 by different concentrations. Conversely, viscosity decreases substantially as the temperature increases from 20 °C to 60 °C. However, based on their thermophysical properties, 0.20 wt % is found to be the optimum concentration. A comparative analysis in terms of heat transfer performance with three different nanofluids in PV/T system shows that, IL+ water/MXene ionanofluid exhibits highest thermal, electrical, and overall heat transfer efficiency compared to water/alumina, palm oil/MXene, and water alone. Maximum electrical efficiency and thermal efficiency are recorded as 13.95% and 81.15% respectively using IL + water/MXene, besides that, heat transfer coefficients are also noticed to increase by 12.6% and 2% when compared to water/alumina and palm oil/MXene respectively. In conclusion, it can be demonstrated that MXene dispersed ionanofluid might be great a prospect in the field of heat transfer applications since they can augment the heat transfer rate considerably which improves system efficiency.
    Matched MeSH terms: Sunlight
  13. Mahmood Raouf R, Abdul Wahab Z, Azowa Ibrahim N, Abidin Talib Z, Chieng BW
    Polymers (Basel), 2016 Apr 14;8(4).
    PMID: 30979233 DOI: 10.3390/polym8040128
    The use of transparent polymers as an alternative to glass has become widespread. However, the direct exposure of these materials to climatic conditions of sunlight and heat decrease the lifetime cost of these products. The aim of this study was to minimize the harm caused by ultraviolet (UV) radiation exposure to transparent poly(methylmethacrylate) (PMMA), which usually leads to changes in the physical and chemical properties of these materials and reduced performance. This was achieved using environmentally friendly cellulose acetate butyrate (CAB). The optical, morphological, and thermal properties of CAB blended with transparent PMMA was studied using UV-VIS spectrophotometry, scanning electron microscopy, X-ray diffraction, dynamic mechanical analysis, and thermal gravimetric analysis. The results show that CAB was able to reduce the effects of UV radiation by making PMMA more transparent to UV light, thereby preventing the negative effects of trapped radiation within the compositional structure, while maintaining the amorphous structure of the blend. The results also show that CAB blended with PMMA led to some properties commensurate with the requirements of research in terms of a slight increase in the value of the modulus and the glass transition temperature for the PMMA/CAB blend.
    Matched MeSH terms: Sunlight
  14. Fatima N, Karimov KS, Qasuria TA, Ibrahim MA
    J Alloys Compd, 2020 Dec 30;849:156702.
    PMID: 32834521 DOI: 10.1016/j.jallcom.2020.156702
    In this research, due to the present pandemic of COVID-19, we are proposing a stable and fixed semitransparent photo-thermoelectric cell (PTEC) module for green energy harvesting. This module is based on the alloy of Bismuth Telluride Selenide (Bi2Te3Se), designed in a press tablet form and characterized under solar energy. Here, both aspects of solar energy i.e., light and heat are utilized for both energy production and water heating. The semitransparent PTEC converts heat energy directly to electrical energy due to the gradient of temperature between two electrodes (top and bottom) of thermoelectric cells. The PTEC is 25% transparent, which can be varied according to the necessity of the utilizer. The X-ray diffraction of material and electric characterization of module i.e., open-circuited voltage (VOC) and Seebeck coefficient were performed. The experimental observations disclose that in the proposed PTEC module with an increment in the average temperature (TAvg) from 34 to 60 °C, results in the rise of VOC ∼ 2.4 times. However, by modifying the size of heat-absorbing top electrode and by increasing the temperature gradient through the addition of water coolant under the bottom electrode, an uplift in the champion device results in as increment of VOC ∼5.5 times and Seebeck coefficient obtained was -250 μV/0C, respectively. Results show that not only the selection of material but also the external modifications in the device highly effective the power efficiency of the devices. The proposed modules can generate electric power from light and utilize the penetrating sunlight inside the room and for the heating of the water which also acts as a coolant. These semitransparent thermoelectric cells can be built-in within windows and roofs of buildings and can potentially contribute to green energy harvesting, in situations where movement is restricted locally or globally.
    Matched MeSH terms: Sunlight
  15. Chew KW, Khoo KS, Foo HT, Chia SR, Walvekar R, Lim SS
    Chemosphere, 2020 Dec 15;268:129322.
    PMID: 33359993 DOI: 10.1016/j.chemosphere.2020.129322
    With the rapid urbanisation happening around the world followed by the massive demand for clean energy resources, green cities play a pivotal role in building a sustainable future for the people. The continuing depletion of natural resources has led to the development of renewable energy with algae as the promising source. The high growth rate of microalgae and their strong bio-fixation ability to convert CO2 into O2 have been gaining attention globally and intensive research has been conducted regarding the microalgae benefits. The focus on potential of microalgae in contributing to the development of green cities is rising. The advantage of microalgae is their ability to gather energy from sunlight and carbon dioxide, followed by transforming the nutrients into biomass and oxygen. This leads to the creation of green cities through algae cultivation as waste and renewable materials can be put to good use. The challenges that arise when using algae and the future prospect in terms of SDGs and economy will also be covered in this review. The future of green cities can be enhanced with the adaptation of algae as the source of renewable plants to create a better outlook of an algae green city.
    Matched MeSH terms: Sunlight
  16. Das A, Barua A, Mohimin MA, Abedin J, Khandaker MU, Al-Mugren KS
    Healthcare (Basel), 2021 Apr 10;9(4).
    PMID: 33920290 DOI: 10.3390/healthcare9040445
    BACKGROUND: The use of a touchless automated hand sanitizer dispenser may play a key role to reduce contagious diseases. The key problem of the conventional ultrasonic and infra-red-based dispensers is their malfunctioning due to the interference of sunlight, vehicle sound, etc. when deployed in busy public places. To overcome such limitations, this study introduced a laser-based sensing device to dispense sanitizer in an automated touchless process.

    METHOD: The dispensing system is based on an Arduino circuit breadboard where an ATmega328p microcontroller was pre-installed. To sense the proximity, a light-dependent resistor (LDR) is used where the laser light is to be blocked after the placement of human hands, hence produced a sharp decrease in the LDR sensor value. Once the LDR sensor value exceeds the lower threshold, the pump is actuated by the microcontroller, and the sanitizer dispenses through the nozzle.

    RESULTS AND DISCUSSION: A novel design and subsequent fabrication of a low-cost, touchless, automated sanitizer dispenser to be used in public places, was demonstrated. The overall performance of the manufactured device was analyzed based on the cost and power consumption, and environmental factors by deploying it in busy public places as well as in indoor environment in major cities in Bangladesh, and found to be more efficient and cost-effective compared to other dispensers available in the market. A comprehensive discussion on this unique design compared to the conventional ultrasonic and infra-red based dispensers, is presented to show its suitability over the commercial ones. The guidelines of the World Health Organization are followed for the preparation of sanitizer liquid. A clear demonstration of the circuitry connections is presented herein, which facilitates the interested individual to manufacture a cost-effective dispenser device in a relatively short time and use it accordingly. Conclusion: This study reveals that the LDR-based automated hand sanitizer dispenser system is a novel concept, and it is cost-effective compared to the conventional ones. The presented device is expected to play a key role in contactless hand disinfection in public places, and reduce the spread of infectious diseases in society.

    Matched MeSH terms: Sunlight
  17. FARAH EILYANA MOHAMED
    MyJurnal
    Solar photocatalysis is a green technology that takes advantage of sustainable solar energy for enhancing oxidation process of numerous harmful water contaminants. In this study, a custom solar driven zinc oxide (ZnO)-mediated photocatalytic system was developed and its efficiency to remove organic contaminants as well as to disinfect selected bacteria was investigated. Methylene blue (MB) dye was used as the model organic contaminant, while Escherichia coli(E.coli) was used as the model fecal coliform bacteria in contaminated water. A series of photodegradation experiments were conducted on water contaminated with either 10 mg/L of MB or ~1010CFU/ml of E.coli. The experiments were completed under sunlight irradiation in the presence of 1 g/L of nano ZnO photocatalyst for up to 6 hours. Using a solar thermal collector, the photoreactor operated in the temperature range of 25 to 50 oC. The findings revealed that the combination of solar thermal with solar photocatalysis usingZnO intensified the degradation of MB and disinfection of E.coli. 98.08% of MB dye and 99.99% of E.coliwere successfully removed from the water within the first 3 hours of treatment. Almost complete removal was eventually achieved after 6 hours of treatment. It is therefore suggested that ZnO-based solar photocatalytic system developed in this study is highly efficient at enhancing water decontamination process.
    Matched MeSH terms: Sunlight
  18. Razali MH, Noor AFM, Yusoff M
    J Nanosci Nanotechnol, 2020 02 01;20(2):965-972.
    PMID: 31383093 DOI: 10.1166/jnn.2020.16944
    In this study, a series of copper-ion-doped titanium dioxide (Cu-ion-doped TiO₂) nanotubes (NTs) were synthesized via a hydrothermal method by the concentration variation of doped Cu ions (0.00, 0.50, 1.00, 2.50, and 5.00 mmol). In addition, the samples were characterized using X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), nitrogen gas adsorption measurements, and ultraviolet-visible (UV-Vis) diffuse-reflectance spectroscopy. The photocatalytic activity of the Cu-iondoped TiO₂ NTs was investigated for the degradation of methyl orange (MO) under sunlight. The results obtained from the structural and morphological studies revealed that, at low concentrations of Cu-doped TiO₂ NTs, Cu is incorporated into the interstitial positions of the TiO₂ lattice, affording a new phase of TiO₂ (hexagonal) instead of the anatase TiO₂ (tetragonal) observed for undoped TiO₂ NTs. EDX analysis confirmed the presence of Cu in the TiO₂-based photocatalyst. All of the investigated samples exhibited a hollow fibrous-like structure, indicative of an NT morphology. The inner and outer diameters of the NTs were 4 nm and 10 nm, respectively. The photocatalysts exhibited a large surface area due to the NT morphology and a type IV isotherm and H3 hysteresis, corresponding to the mesopores and slit-shaped pores. The Cu-ion-doped TiO₂ NTs were excited by sunlight because of their low bandgap energy; and after the incorporation of Cu ions into the interstitial positions of the TiO₂ lattice, the NTs exhibited high visible-light activity owing to the low bandgap.
    Matched MeSH terms: Sunlight
  19. Chaturvedi D, Singh VK
    Trop Life Sci Res, 2016 Aug;27(2):25-36.
    PMID: 27688849 DOI: 10.21315/tlsr2016.27.2.3
    Fasciolosis is a water and food-borne disease caused by the liver fluke Fasciola hepatica and Fasciola gigantica. This disease is widespread in different parts of the world. Lymnaeidae and Planorbidae snails are the intermediate hosts of these flukes. Snail population management is a good tool to control fasciolosis because gastropods represent the weakest link in the life-cycle of trematodes. Chlorophyll can be extracted from any green plant. Chlorophyllin was prepared from spinach in 100% ethanol by using different types of chemicals. The chlorophyll obtained from spinach was transformed into water-soluble chlorophyllin. In the present paper, toxicity of chlorophyllin against the snail Lymnaea acuminata was time and concentration dependent. The toxicity of extracted and pure chlorophyllin at continuous 4 h exposure of sunlight was highest with lethal concentration (LC50) of 331.01 mg/L and 2.60 mg/L, respectively, than discontinuous exposure of sunlight up to 8 h with LC50 of 357.04 mg/L and 4.94 mg/L, respectively. Toxicity of extracted chlorophyllin was noted in the presence of different monochromatic visible lights. The highest toxicity was noted in yellow light (96 h, LC50 392.77 mg/L) and the lowest in green light (96 h, LC50 833.02 mg/L). Chlorophyllin in combination with solar radiation or different wavelength of monochromatic visible lights may become a latent remedy against the snail L. acuminata. It was demonstrated that chlorophyllin was more toxic in sunlight. Chlorophyllin is ecologically safe and more economical than synthetic molluscicides which have the potential to control the incidence of fasciolosis in developing countries.
    Matched MeSH terms: Sunlight
  20. Khamsiah, N., Lai, N.S., Nurfarhanim, M., Nor Aimi, A.R., Mohd Syazwan, C. S., Goon, J.A.
    Medicine & Health, 2012;7(2):84-96.
    MyJurnal
    The Malaysian skincare industry is growing rapidly with a vast number of new sunscreens being produced annually. Inadequate skincare regulations and lack of enforcement have resulted in the overrating of sunscreens’ quality. The objectives of this study were to evaluate the efficacy and safety of the local and international sunscreens and to determine the effects of adding concentrated antioxidants into them. Three local and three internationally manufactured sunscreens were tested for the in vitro Ultraviolet A protection factor (UVAPF), Sun Protection Factor (SPF) and photostability. The creams were spread onto roughened polymethylmethacrylate plates where the absorbance was measured using a spectrophotometer before and after two hours of sunlight irradiation. The procedure was repeated combining available concentrated vitamin C and E creams. International sunscreens were found to have more accurate SPF labels (p=0.009) while local sunscreens were found to be more photostable (p=0.003). However, both sunscreens had inadequate UVAPF (p=0.471). Vitamin C enhanced the SPF values (p= 0.04) of both groups of sunscreens while vitamin E enhanced their photostability (p=0.000). Interestingly, combining vitamins C and E rich creams with the sunscreens had no effect on the SPF and UVAPF values as compared to the use of a single vitamin. More importantly, the combination of vitamins decreased the photostability (p=0.002) of sunscreens as compared to the addition of vitamin E alone. In conclusion, photoprotection is best achieved when sunscreens are used together with creams containing either vitamin C or E alone.
    Matched MeSH terms: Sunlight
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