The effect of ribose-induced Maillard reaction on the physical and mechanical properties of gelatin films was investigated. Bovine gelatin solution (5 g/100 mL) containing glycerol and sorbitol (1:1) was mixed with 20% (R20), 40% ribose (R40), or 40% sucrose (S40) (weight % is based on gelatin dry weight) followed by heating (90ºC, 2 h) and oven drying to produce dried gelatin films. R20 and R40 films were brownish in color with lower light transparency, while CF (control film; without sugars) and S40 were colorless and had higher transparency. Tensile strength and Young Modulus values of the films were in the order; CF > R20 > R40 > S40, while elongation at break was in the order; R40 > S40 > R20 > CF. Water solubility and swelling percentages of the films were in the order; CF > S40 > R20 > R40, indicating the occurrence of insoluble “Maillard complexes” within R20 and R40 films. R20 and R40 films showed maximum light absorption at wavelength of 200 − 350 nm, whilst S40 and CF showed maximum absorbance at 200 − 250 nm. The addition of ribose yielded gelatin films with increased protection against UV light, even though the presence of sugars might had disrupted the inter connection of junction zones and decrease in mechanical properties. Occurrence of the Maillard reaction within R20 and R40 films could be the main reason for differences in physical and mechanical properties of films containing ribose that were formed from heated film-forming solutions.
Poly(lactic acid) (PLA)-based nanocomposites filled with graphene nanoplatelets (xGnP) that contains epoxidized palm oil (EPO) as plasticizer were prepared by melt blending method. PLA was first plasticized by EPO to improve its flexibility and thereby overcome its problem of brittleness. Then, xGnP was incoporated into plasticized PLA to enhance its mechanical properties. Plasticized and nanofilled PLA nanocomposites (PLA/EPO/xGnP) showed improvement in the elongation at break by 3322% and 61% compared to pristine PLA and PLA/EPO, respectively. The use of EPO and xGnP increases the mobility of the polymeric chains, thereby improving the flexibility and plastic deformation of PLA. The nanocomposites also resulted in an increase of up to 26.5% in the tensile strength compared with PLA/EPO blend. XRD pattern showed the presence of peak around 26.5° in PLA/EPO/xGnP nanocomposites which corresponds to characteristic peak of graphene nanoplatelets. Plasticized PLA reinforced with xGnP showed that increasing the xGnP content triggers a substantial increase in thermal stability. Crystallinity of the nanocomposites as well as cold crystallization and melting temperature did not show any significant changes upon addition of xGnP. However, there was a significant decrease of glass transition temperature up to 0.3wt% of xGnP incorporation. The TEM micrograph of PLA/EPO/xGnP shows that the xGnP was uniformly dispersed in the PLA matrix and no obvious aggregation was observed.
Acacia mangium, a fast growing tree is widely planted in Malaysia. Converting Acacia wood into nanocellulose could create new value added products for forest-based industry. Nanocrystalline cellulose (NCC) was prepared from Acacia mangium wood pulp via 64wt% sulfuric acid hydrolysis. Prior to acid hydrolysis, Acacia mangium was subjected to pulping followed by bleaching in order to remove non-cellulosic fragments. Acid hydrolysis was carried out on bleached pulp to produce the needle-like NCC with 79% crystallinity and aspect ratio of 26. The resulting NCC was mixed with PVA as a reinforcement material. Incorporation of 2% NCC improved the tensile of the NCC-PVA film by 30%.
This study focuses on the mechanical effect of different composition of polymer blend. Polymer blend of high density polyethylene (HDPE) and ethylene propylene rubber (EPR) were selected and varied by three different compositions which are 70:30, 50:50 and 30:70. HDPE-EPR blend is believed to be the best material for sole shoe. In which, HDPE has good flexibility while, EPR can maintain optimum performance at high and low temperature as well as provide better gripping characteristic that suits for insole and outsole sport shoe. On the other hand, the time efficiency of electron beam radiation on these polymer blends helps in improving the croslinking of HDPE-EPR blend. The aim of this paper was to find the optimum composition of electron beam irradiated polymer blends for sole shoes especially in sports application. These irradiated polymer blends were produced by melt blending, underwent compression moulding and then were irradiated by electron beam at 100 kGy/s. Mechanical test of tensile and hardness test were investigated and the morphology of the failure fracture was analysed by field emission scanning electron microscopy (FESEM). The polymer blend with 70% of HDPE and 30% of EPR showed the optimum result of tensile strength, tensile modulus and hardness as well as ductile failure image.
This study was carried out to determine the physicochemical properties of carboxymethyl cellulose (CMC) derived from cellulose of palm oil empty fruit bunch (EFB) and its use asa film-coating agent. Samples were prepared at various concentrations and then their physicochemical properties were studied including the viscosity, pH, tensile strength of films, surface properties of the films and dissolution studies on coated tablets. CMC EFB showed lower viscosity than commercial CMC product at the concentration of 1%, 2% and 3% with the values of 44.0cp, 299.9cp, 358.9cp and 90.0cp, 689.9cp, 5569.0cp respectively. The tensile strength of the films for CMC EFB were 7.85MPa, 14.79MPa, 10.36MPa while the commercial CMC exhibited higher values of 21.72MPa, 35.14MPa and 26.9MPa at similar concentration. The scanning electron microscope showed different surface properties of the films for both of them where the commercial CMC is smoother in texture and very transparent unlike its counterpart. However, dissolution studies on paracetamol tablets coated using the samples showed no significant difference (p>0.05) in drug release profile between the two materials. Hence, CMC EFB has a greater potential to be developed as a competitive tablet-coating agent despite the differences in its physicochemical properties.
Austempering is one of the trendiest heat treatment processes to promote the strength and toughness of ductile iron. However, such practice is complex because it involves using aqueous solutions as quenchant (salt bath solution). This study was conducted to analyse the heat treatment of the combination processes of annealing-austenitising and evaluate the correlation between microstructure constituent and hardness of the ductile iron. Ductile iron samples in form of double cylinder was produced by conventional CO2 sand casting method. The new heat treatment process was started by annealed at 873 K for 1.8 ks before being oil quenched. Subsequently, the samples were austenitised at austenitising temperatures 1123 K, 1173 K and 1223 K for 3.6 ks respectively before being immediately oil quenched to room temperature. A series of microstructure analysis tests, including optical microscopy and X-ray diffraction (XRD) was applied. Vickers microhardness tester was used to measure the hardness for each microstructure constituent. The results showed that ductile iron matrix transforms to martensitic during heat treatment of annealing-austenitising combination processes, which in turn contributes to increasing microhardness of martensite and the bulk hardness of ductile iron.
The nano-cellulose derived nano-biofilm keeps a magnificent role in medical, biomedical, bioengineering and pharmaceutical industries. Plant biomaterial is naturally organic and biodegradable. This study has been highlighted as one of the strategy introducing biomass based nano-bioplastic (nanobiofilm) to solve dependency on petroleum and environment pollution because of non-degradable plastic. The data study was carried out to investigate the nano-biopolymer (nanocellulose) based nano-biofilm data from corn leaf biomass coming after bioprocess technology without chemicals. Corn leaf biomass was used to produce biodegradable nano-bioplastic for medical and biomedical and other industrial uses. Data on water absorption, odor, pH, cellulose content, shape and firmness, color coating and tensile strength test have been exhibited under standardization of ASTM (American standard for testing and materials). Moreover, the chemical elements of nanobiofilm like K+, CO3--, Cl-, Na+ showed standard data using the EN (166).
The nanocellulose derived biodegradable plant biomaterial as nano-coating can be used in the medical, biomedical cosmetics, and bioengineering products. Bio-plastic and some synthetic derived materials are edible and naturally biodegradable. The study was conducted to investigate edible nano-biopolymer based nano-coating of capsules and drugs or other definite biomedical materials from corn leaf biomass. Corn leaf biomass was used as an innovative sample to produce edible nano-coating bioplastic for drug and capsule coating and other industrial uses. The data show the negligible water 0.01% absorbed by bio-plastic nanocoating. Odor represented by burning test was under the completely standard based on ASTM. Moreover, data on color coating, tensile strength, pH, cellulose content have been shown under standard value of ASTM (American standard for testing and materials) standard. In addition to that data on the chemical element test like K+,
CO
3
- -
, Cl-, Na+ exhibited positive data compared to the synthetic plastic in the laboratory using the EN (166)) standardization. Therefore, it can be concluded that both organic (cellulose and starch) based edible nano-coating bioplastic may be used for drug and capsule coating as biomedical and medical components in the pharmaceutical industries.
The objective of this study was to develop biodegradable active film to improve the shelf-life of minimally processed fresh-produce. Guar gum (GG) based films with improved properties were fabricated by employing tween-80 (0.88%) as emulsifier, nanoclay (13.9%) as reinforcement, beeswax (1.21%) for hydrophobicity, glycerol (3.07%) as plasticizer, and grape pomace extract (5%) as active ingredient (%w/w of GG). Active films had a tensile strength of 122 MPa and water vapor transmission rate of 69 gm-2d-1. Films demonstrated significant antimicrobial activity against Escherichia coli, Staphylococcus aureus, Bacillus cereus, and Salmonella Typhimurium. The 2 kGy irradiated minimally processed pomegranate arils packed in film demonstrated a shelf-life of 12 days as compared to 4 days for unirradiated samples. The observed improvement in shelf-life was due to a radiation-induced release of antimicrobial volatiles from active films as confirmed by headspace analysis using GC-MS. Suitability of active films for food irradiation applications is thus demonstrated.
Present study, deals about isolation and characterization of cellulose nanofibers (CNFs) from the Northern Bleached Softwood Kraft (NBSK) pulp, fabrication by hand lay-up technique and characterization of fabricated epoxy nanocomposites at different filler loadings (0.5%, 0.75%, 1% by wt.). The effect of CNFs loading on mechanical (tensile, impact and flexural), morphological (scanning electron microscope and transmission electron microscope) and structural (XRD and FTIR) properties of epoxy composites were investigated. FTIR analysis confirms the introduction of CNFs into the epoxy matrix while no considerable change in the crystallinity and diffraction peaks of epoxy composites were observed by the XRD patterns. Additions of CNFs considerably enhance the mechanical properties of epoxy composites but a remarkable improvement is observed for 0.75% CNFs as compared to the rest epoxy nanocomposites. In addition, the electron micrographs revealed the perfect distribution and dispersion of CNFs in the epoxy matrix for the 0.75% CNFs/epoxy nanocomposites, while the existence of voids and agglomerations were observed beyond 0.75% CNFs filler loadings. Overall results analysis clearly revealed that the 0.75% CNFs filler loading is best and effective with respect to rest to enhance the mechanical and structural properties of the epoxy composites.
The synergistic effect of using κ-carrageenan bionanocomposites with the hybridization of cellulose nanocrystals (CNCs) and organically modified montmorillonite (OMMT) reinforcements was studied. The effects of different reinforcements and filler contents were evaluated through mechanical testing, and morphological and water uptake properties. The tensile strength and Young's modulus of both bionanocomposites increased with filler loading and optimized at 4%. OMMT incorporation into the κ-carrageenan/CNCs bionanocomposites resulted in further mechanical property improvement with an optimum ratio of 1:1 (CNCs:OMMT) while maintaining high film transparency. X-ray diffraction and morphological analyses revealed that intercalation occurred between the κ-carrageenan bionanocomposite matrix and OMMT. The water uptake of the κ-carrageenan bionanocomposites was significantly reduced by the addition of both CNCs and OMMT. The enhancements in the mechanical properties and performance of the hybrid bionanocomposite indicate compatibility among the reinforcement, biopolymer, and well-dispersed nanoparticles. This renders the hybrid CNC/OMMT/κ-carrageenan nanocomposites extremely promising for food packaging applications.
In this study, a wound dressing based on polyurethane (PU) blended with copper sulphate nanofibers was developed using an electrospinning technique. The prepared PU and PU nanocomposites showed smooth fibers without any bead defects. The prepared nanocomposites showed smaller fiber (663 ± 156.30 nm) and pore (888 ± 70.93 nm) diameter compared to the pristine PU (fiber diameter 1159 ± 147.48 nm and pore diameter 1087 ± 62.51 nm). The interaction of PU with copper sulphate was evident in the infrared spectrum through hydrogen-bond formation. Thermal analysis displayed enhanced weight residue at higher temperature suggesting interaction of PU with copper sulphate. The contact angle measurements revealed the hydrophilic nature of the prepared nanocomposites (71° ± 2.309°) compared with pure PU (100° ± 0.5774°). The addition of copper sulphate into the PU matrix increased the surface roughness, as revealed in the atomic force microscopy (AFM) analysis. Mechanical testing demonstrated the enhanced tensile strength behavior of the fabricated nanocomposites (18.58 MPa) compared with the pristine PU (7.12 MPa). The coagulation assays indicated the enhanced blood compatibility of the developed nanocomposites [activated partial thromboplastin time (APTT)-179 ± 3.606 s and partial thromboplastin time (PT)-105 ± 2.646 s] by showing a prolonged blood clotting time compared with the pristine PU (APTT-147.7 ± 3.512 s and PT-84.67 ± 2.517 s). Furthermore, the hemolysis and cytotoxicity studies suggested a less toxicity nature of prepared nanocomposites by displaying low hemolytic index and enhanced cell viability rates compared with the PU membrane. It was observed that the fabricated novel wound dressing possesses better physicochemical and enhanced blood compatibility properties, and may be utilized for wound-healing applications.
The main focus of this study was to obtain the optimum alkaline treatment for banana fibre and the its effect on the mechanical and chemical properties of banana fibre, its surface topography, its heat resistivity, as well as its interfacial bonding with epoxy matrix. Banana fibre was treated with sodium hydroxide (NaOH) under various treatment conditions. The treated fibres were characterised using FTIR spectroscopy. The morphology of a single fibre observed under a Digital Image Analyser indicated slight reduction in fibre diameter with increasing NaOH concentration. The Scanning Electron Microscope (SEM) results showed the deteriorating effect of alkali, which can be seen from the removal of impurities and increment in surface roughness. The mechanical analysis indicates that 6% NaOH treatment with a two-hour immersion time gave the highest tensile strength. The adhesion between single fibre and epoxy resin was analysed through the micro-droplet test. It was found that 6% NaOH treatment with a two-hour immersion yielded the highest interfacial shear stress of 3.96 MPa. The TGA analysis implies that alkaline treatment improved the thermal and heat resistivity of the fibre.
The recognition of nanocellulose has been prominent in recent years as prospect materials, yet the ineffectiveness of nanocellulose to disperse in an organic solvent has restricted its utilization, especially as a reinforcement in polymer nanocomposite. In this study, cellulose has been isolated and defibrillated as cellulose nanofibrils (CNF) from oil palm empty fruit bunch (EFB) fibers. Subsequently, to enhance its compatibility with UV-curable polyurethane (PU)-based resin, the surface hydrophilicity of CNF has been tailored with polyethylene glycol (PEG), as well as reduced graphene oxide (rGO). The dispersibility of reinforced modified CNF in UV-curable PU was examined through the transmittance interruption of resin, chemical, and mechanical properties of the composite printed using the stereolithographic technique. Evidently, the enhanced compatibility of modified CNF and UV-curable PU was shown to improve the tensile strength and hardness of the composites by 37% and 129%, respectively.
In this work, the optimum filler loading to prepare epoxy/organoclay nanocomposites by the in-situ polymerization method was studied. Bi-functionalized montmorillonite at different filler loading (0.5, 1.0, 2.0, 4.0 wt %) was dispersed in epoxy resin by using a high shear speed homogenizer. The effect on morphology, thermal, dynamic mechanical, and tensile properties of the epoxy/organoclay nanocomposites were studied in this work. Wide-angle X-ray scattering (WAXS) and field emission scanning electron microscope (FESEM) studies revealed that possible intercalated structures were obtained in epoxy/organoclay nanocomposites. Thermogravimetric analysis (TGA) shows that epoxy/organoclay nanocomposites exhibit higher thermal stability at the maximum and final decomposition temperature, as well as higher char content, compared to pristine epoxy. The dynamic mechanical analysis (DMA) indicate that storage modulus (E'), loss modulus (E″), cross-link density and glass transition temperature (Tg) of the nanocomposites were improved with organoclay loading up to 1 wt %. Beyond this loading limit, the deterioration of properties was observed. A similar trend was also observed on tensile strength and modulus. We concluded from this study that organoclay loading up to 1 wt % is suitable for further study to fabricate hybrid nanocomposites for various applications.
The conventional isolation of cellulose nanofibers (CNFs) process involves high energy input which leads to compromising the pulp fiber's physical and chemical properties, in addition to the issue of elemental chlorine-based bleaching, which is associated with serious environmental issues. This study investigates the characteristic functional properties of CNFs extracted via total chlorine-free (TCF) bleached kenaf fiber followed by an eco-friendly supercritical carbon dioxide (SC-CO2) treatment process. The Fourier transmission infra-red FTIR spectra result gave remarkable effective delignification of the kenaf fiber as the treatment progressed. TEM images showed that the extracted CNFs have a diameter in the range of 10-15 nm and length of up to several micrometers, and thereby proved that the supercritical carbon dioxide pretreatment followed by mild acid hydrolysis is an efficient technique to extract CNFs from the plant biomass. XRD analysis revealed that crystallinity of the fiber was enhanced after each treatment and the obtained crystallinity index of the raw fiber, alkali treated fiber, bleached fiber, and cellulose nanofiber were 33.2%, 54.6%, 88.4%, and 92.8% respectively. SEM images showed that amorphous portions like hemicellulose and lignin were removed completely after the alkali and bleaching treatment, respectively. Moreover, we fabricated a series of cellulose nanopapers using the extracted CNFs suspension via a simple vacuum filtration technique. The fabricated cellulose nanopaper exhibited a good tensile strength of 75.7 MPa at 2.45% strain.
Epoxidized natural rubber (ENR-50) has been used as a compatibilizer for natural rubber-recycled acrylonitrile-butadiene
rubber (NR/NBRr) blends, vulcanized by sulfur. NBR gloves have excellent resistance to punctures, tear and many types
of chemicals, while NR has good physical and mechanical properties. Incorporation of ENR-50 into the rubber blends
has improved processability, stiffness, resilience and excellent oil resistance. NR/NBRr blends were prepared by two-roll
mill with five different compositions with the ENR-50 content fixed at 10 phr. Cure characteristics, mechanical properties
and morphology (SEM) studies were performed to determine the compatibility of NR/NBRr blends in the presence of ENR-
50. The cure characteristics showed that NR/NBRr blends with the presence of ENR-50 have lower scorch time (ts2) and
cure time (t90) than NR/NBRr blends without ENR-50. However, the NR/NBRr blends with ENR-50 exhibited higher minimum
torque (ML
) and maximum torque (MH) which indicated difficult processability of the blends after compatibilization.
Incorporation of ENR-50 into NR/NBRr blends improved all the tensile properties (tensile strength, tensile modulus and
elongation at break) compared with NR/NBRr blends without ENR-50. The improvement in hardness upon compatibilization
is due to an increase in crosslink density. Scanning electron microscopy (SEM images) of the fracture surfaces indicates
that, with the addition of ENR-50 in NR/NBRr blends, better adhesion between NR and NBRr was obtained, thus improving
the compatibility of NR/NBRr blends.
Cellulose nanocrystals (CNC) from mengkuang leaves (Pandanus tectorius) were investigated as potential reinforcement
in poly(vinyl chloride) (PVC) matrix. The surface of CNC was modified with silane coupling agent to improve fillermatrix
adhesion. Solution casting method was used to prepare PVC nanocomposites with various amounts of modified
(SCNC) and unmodified (CNC) nanocrystals. Both SCNC and CNC were examined by Fourier transform infrared (FTIR)
spectroscopy and X-ray diffraction (XRD) which showed that surface chemical modification has occurred. An increase
in tensile strength was observed with the addition of SCNC compared to the CNC. However, the elongation at break of the
nanocomposites was found to decrease with the increase of both fillers loading. An increasing trend was observed in the
tensile modulus with the addition of CNC to the PVC matrix, but decreasing with the addition of SCNC. The morphology
of a fractured surface of nanocomposites showed silane modification reduced the number of voids in the structure of
PVC. The observation indicated the adhesion between the fiber and the matrix had improved upon surface modification
of the nanocrystals with silane.
The cellulose microfibers (CMF) from water hyacinth (WH) fiber as a filler in sago starch (SS) biocomposites was investigated. The CMF was isolated by pulping, bleaching and acid hydrolysis methods. The addition of CMF in sago matrix was varied i.e. 0, 5, 10, 15 and 20 wt%. Biocomposites were made by using solution casting and glycerol as a plasticizer. The biocomposites were also determined by tensile test, FTIR, X-Ray, thermogravimetric, SEM, and soil burial tests. The results show that the SS15CMF sample has the highest tensile strength of 10.23 MPa than those other samples. Scanning Electron Microscope (SEM) images show that the strong interaction was formed between CMF WH and matrix. Fourier Transform Infra-red (FTIR) indicated that the functional group of biocomposites was a hydrophilic cluster. The addition of CMF WH in sago starch biocomposites lead to the moisture barrier, crystallinity, and thermal stability increased; it is due to the pure sago starch film was more rapidly degraded than its biocomposites.
In relation to the use of retrofit materials on damaged constructions, application on earthquake-resistant buildings, and for the strengthening and rehabilitation on weakened regions, there is a need for a more superior material than concrete. Application sites include beam-column joints, corbels, link-slabs, deep beams, support regions and dapped-end areas. Fiber reinforced engineered cementitious composites (FR-ECC) can address this issue, because FR-ECC is one of the composite materials that has high strength, ductility and durability. In order to develop FR-ECC, this study was done to investigate the effect of adding quartz powder on the compressive strength capacity and properties of FR-ECC through the use of polyvinyl alcohol (PVA) and steel fibers. The volume fraction of fiber was set to 0%-2%. To support the friendly environment, FR-ECC uses by-product materials such as fly ash and silica fume, with a cement content less than 600 kg/m3. In terms of the experimental investigation on FR-ECC, this work conducted the fresh property tests showing that PVA fibers have quite an influence on ECC workability, due to their hydrophilic behavior. By adjusting the superplasticizer (SP) content, the consistency and high workability of the ECC mixes have been achieved and maintained. The test results indicated that the PVA and steel fibers-based ECC mixes can be classified as self-compacting composites and high early compressive strength composites. Significantly, addition of quartz powder into the ECC mixes increased the compressive strength ratio of the ECC samples up to 1.0747. Furthermore, the steel fiber-based ECC samples exhibited greater compressive strength than the PVA fibers-based ECC samples with the strength ratio of 1.1760. Due to effect of the pozzolanic reaction, the fibers dispersion and orientation in the fresh ECC mixes, so that the cementitious matrices provided the high strength on the FR-ECC samples. During the compression loading, the bulging effect always occurred before the failures of the fibers-based ECC samples. No spalling occurred at the time of rupture and the collapse occurred slowly. Thus, FR-ECC has provided unique characteristics, which will reduce the high cost of maintenance.