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  1. Fulltext Orange peels magnetic activate carbon (MG-OPAC) composite formation for toxic chromium absorption from wastewater
    Khalil A, Salem M, Ragab S, Sillanpää M, El Nemr A
    Sci Rep, 2023 Feb 28;13(1):3402.
    PMID: 36854794 DOI: 10.1038/s41598-023-30161-6
    This work prepared a composite of orange peels magnetic activated carbon (MG-OPAC). The prepared composite was categorized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), Energy-dispersive X-ray spectroscopy (EDX), Scanning Electron Microscopy (SEM) and vibrating-sample magnetometer (VSM) analyses. The MG-OPAC composite showed the surface area (155.09 m2/g), the total volume of pores (0.1768 cm3/g), and the mean diameter of pores (4.5604 nm). The saturation magnetization (Ms = 17.283 emu/g), remanence (Mr = 0.28999 emu/g) and coercivity (Hc = 13.714 G) were reported for the prepared MG-OPAC. Likewise, at room temperature, the MG-OPAC was in a super-paramagnetic state, which could be collected within 5 S (S) with an outside magnetic field. Influence of time of contact, absorbent dose, starting concentration of Cr6+ ions, and pH were tested to adjust the absorption process. The absorption behavior of MG-OPAC for hexavalent chromium was investigated by Langmuir (LIM), Freundlich (FIM) and Temkin (TIM) isotherm models (IMs). Applicability of LIM specifies that Cr6+ ions absorption procedure may be monolayer absorption. The maximum monolayer capacity (Qm) premeditated by LIM was 277.8 mg/g. Similarly, the absorption process was tested with different kinetic models like intraparticle diffusion (IPDM), pseudo-first-order (PFOM), Elovich (EM), pseudo-second-order (PSOM), and Film diffusion (FDM). The PSOM was best fitted to the experimental results of Cr6+ ions absorption with R2 ranging between 0.992 and 1.
  2. Implication of CDKAL1 single-nucleotide polymorphism rs 9465871 in obese and non-obese Egyptian children
    Ismail NA, Ragab S, Abd El Dayem SM, Baky ANAE, Hamed M, Ahmed Kamel S, et al.
    Med J Malaysia, 2018 10;73(5):286-290.
    PMID: 30350806
    INTRODUCTION: CDKAL1 single-nucleotide polymorphism rs 9465871variant is a risk locus for Type 2 Diabetes (T2DM).The study evaluated the associations of CDKAL1- rs9465871 with glycosylated hemoglobin A1C Level (HbA1c), fasting insulin level, insulin resistance and metabolic syndrome among obese and non- obese Egyptian children.

    MATERIALS AND METHODS: The study included 43 obese children and 40 normal weight children. Anthropometric body measurements, bio-specimen and biochemistry assays were done. Genotyping of rs9465871 (CDKAL1) was conducted.

    RESULTS: The percentages of the CC, CT, and TT genotypes of rs9465871in the lean children were 15%, 42.5%, and 42.5%, respectively. Regarding obese children, the frequencies were 18.6%, 58.1% and 23.3% respectively with no significant statistical difference. Comparison between the CDKAL1 rs 9465871 polymorphism showed that the highest value of fasting insulin was recorded in CC genotype (22.80± 15.18 [uIU/mL] P

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