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  1. Fulltext Synthesis and characterization of chitosan-modified membrane for urea slow-release fertilizers
    Cahyaningrum SE, Lusiana RA, Natsir TA, Muhaimin FI, Wardana AP, Purnamasari AP, et al.
    Heliyon, 2024 Aug 15;10(15):e34981.
    PMID: 39165941 DOI: 10.1016/j.heliyon.2024.e34981
    BACKGROUND: Urea is a fertilizer widely used by farmers, especially vegetable farmers, due to its high nitrogen content, around 46 %. However, plants only use a small amount of nitrogen, a maximum of 35 %, while the remaining nitrogen is wasted and released into the environment. Undeniably, it causes increases production costs and environmental problems. A slow-release urea fertilizer (SRF) has been formulated to resolve these issues.

    METHODS: In this study, the membrane was made of chitosan with several crosslinking agents such as Tripolyphosphate (TPP). In addition, calcium ion bonds are expected to increase the interaction with urea fertilizer through the encapsulation process.

    THE RESULTS: Our data showed that urea slow-release fertilizer (SRF) with the chitosan/TPP/Ca membrane, was successfully synthesized. This membrane has the characteristics of a thin white layer that is transparent. The physical and chemical characterization of SRF membranes with various coating membrane variations showed that the chitosan/TPP/Ca-urea membrane has Young's modulus of 7.75-22.05 N/mm2, swelling of 109.52-132.62 % and porosity of 0.756-1.06 %. Functional group analysis shows that several spectral changes indicate the presence of crosslinking process between the chitosan functional groups and TPP. The urea release results show that the membrane is released through a diffusion mechanism. Furthermore, SEM results show that these membranes have pores with various shapes and sizes.

    CONCLUSION: Based on the result, it can be concluded that chitosan membrane modification with the addition of TPP and calcium oxide provides improved membrane characteristic cs including degree of development, hydrophobicity, membrane stress, and nitrogen release on the membrane. This membrane shows is indicating suitability as a slow-release fertilizer.

  2. Permeability improvement of polyethersulfone-polietylene glycol (PEG-PES) flat sheet type membranes by tripolyphosphate-crosslinked chitosan (TPP-CS) coating
    Lusiana RA, Sangkota VDA, Sasongko NA, Gunawan G, Wijaya AR, Santosa SJ, et al.
    Int J Biol Macromol, 2020 Jun 01;152:633-644.
    PMID: 32112845 DOI: 10.1016/j.ijbiomac.2020.02.290
    In this study, improvement of urea and creatinine permeability of polyethersulfone (PES) membrane by coating with synthesized tripolyphosphate-crosslinked chitosan (TPP-CS) has been conducted. Original and modified membranes, e.g. pristine PES, polyethersulfone-polyethylene glycol (PES-PEG) and PES-PEG/TPP-CS membranes were characterized using FTIR, DTG, SEM, AFM, water uptake, contact angles, porosity measurement, tensile strength test and permeation tests against urea and creatinine. The results show that the PES modification by TPP-CS coating has been successfully carried out. The water uptake ability, hydrophilicity and porosity of the modified membranes increase significantly to a greater degree. All modified membranes have good thermal stability and tensile strength and their permeation ability towards urea and creatinine increase with the increasing concentration of TPP-CS. PES membrane has urea clearance ability of 7.36 mg/dL and creatinine of 0.014 mg/dL; membrane PES-PEG shows urea clearance of 11.87 mg/dL and creatinine of 0.32 mg/dL; while PES-PEG/TPP-CS membrane gives urea clearance of 20.87-36.40 mg/dL and creatinine in the range of 0.52-0.78 mg/dL. These results suggest that the PES-PEG membrane coated with TPP-CS is superior and can be used as potential material for hemodialysis membrane.
  3. Synthesis and characterisation of composite sulphonated polyurethane/polyethersulphone membrane for blood purification application
    Mansur S, Othman MHD, Ismail AF, Kadir SHSA, Goh PS, Hasbullah H, et al.
    Mater Sci Eng C Mater Biol Appl, 2019 Jun;99:491-504.
    PMID: 30889724 DOI: 10.1016/j.msec.2019.01.092
    Polyurethane (PU) with three different functional groups: carboxyl, hydroxyl and sulphonyl group on its molecular structure were synthesised in this work. The synthesised material suppresses blood clotting and exhibits anticoagulant characteristics due to the presence of the important anionic groups. The synthesised PU was blended with polyethersulphone (PES) and fabricated into flat-sheet membrane to study the physico-chemical and biocompatibility properties of the PES membrane for blood purification application. PES-PU flat-sheet membranes were fabricated via the dry-wet phase separation technique. Different loading of PU (0, 1, 2, 3, 4, and 5%) blended with PES was studied and compared. Based on the in-vitro biocompatibility analysis of the membrane, it can be suggested that the membrane incorporated with PU has better anticoagulant properties compared to the pristine PES membrane. PU incorporation prolonged the clotting time, decreased the formation of thrombin, decreased soluble complement component 3a (C3a) generation and suppressed platelet adhesion and aggregation. The anionic groups on the membrane surface might bind to coagulation factors (antithrombin) and the calcium ions, Ca2+ and thus improve anticoagulant ability. Based on both physico-chemical and in-vitro studied, 4% loading of PU is the optimum loading for incorporation with PES membrane. These results suggested that the blended PES-PU membranes with good haemocompatibility allowed practical application in the field of blood purification.
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