Semiconductor oxides such as titanium dioxide (TiO2) and zinc oxide (ZnO) are used as the photocatalyst for removing contaminants. In addition, TiO2 and ZnO nanoparticles in the suspension form makes it difficult to be recovered and recycled. This study was conducted to investigate the efficiency of immobilizing TiO2 and ZnO nanoparticles in epoxy beads. The immobilization process using different ratios of photocatalysts TiO2/ZnO (1:0, 3:1, 1:1, 1:3 and 0:1) fixed on epoxy material. These epoxy beads were used for dye removal in photocatalysis using methylene blue (MB) solution at a concentration of 10mg/L. Besides, epoxy beads also characterized using scanning electron microscope (SEM), attenuated total reflection Fourier-transform infrared (ATR-FTIR) spectroscopy and thermogravimetric analysis (TGA). The results showed that the highly recommended epoxy bead is 3:1 ratio of TiO2/ZnO because it has good performance in dye degradation that proved from reducing concentration of MB to 2.4mg/L (76%). However, TiO2/ZnO characterization of 3:1 by SEM show on the surface the particle are found to be spherical in shape which is relatively high efficiency for the degradation, ATR-FTIR pattern in broad band 4000 cm-1 - 400cm-1 which correspond to hydroxyl stretching to be adsorbed at peak (474.49 cm-1 - 3722.61cm-1) respectively to the optimum for the degradation and TGA rate of change are 5mg to 2.5mg that residue (49.78%) due to decomposition or oxidation from mass loss. These findings are very effective and economical technique to be cost saving and highly efficient photocatalyst.
Renewable materials have some bearing on the environment and have since increased research works related to polymer composites. This work was conducted to investigate the effects of interwoven kenaf fibres and the use of kenaf fibres in composites. In this research, interwoven between kenaf and polyethylene terephthalate (PET) was prepared and epoxy was used as the polymer matrix to form composites. The kenaf fibre composites with various kenaf fibre contents (2, 5, 8, and 10 wt %) interwoven with (PET) fibres were prepared by using open mould method. The properties of kenaf/PET/epoxy composites (KPTE) were studied. The kenaf fibre composites characterization was determined based on their mechanical properties, water absorption, morphology and thermal properties. The tensile strength test was performed using Testometric machine. The finding shows that the strength increases as the amount of kenaf fibres in the composites increases. The composites with 10% kenaf fibres interwoven PET displayed the highest tensile strength (85.3 ± 2.9 MPa) while unfilled epoxy show the lowest tensile strength (64.1 ± 16.5 MPa). The addition of kenaf fibres minimally increases the water absorption up to about 1.4%. The increases of kenaf fibres also reduces the overall thermal stability of the composites compared to the PET and epoxy resin composites. The morphology properties of KPTE composites support the tensile properties surface of the composites. This study assists to propose the kenaf fibres as a potential filler for properties improvements in epoxy-based composites contributing to the development of another environment-friendly material.
This aim of this study is to study the effects of various contents of Automotive Windscreen Glass Waste Powder (WGWP) as a cement replacement. Mortar incorporating several compositions of WGWP (0%, 5%, 10%, 15% and 20%) by weight of cement was prepared. Three batching systems of cement to sand (C:S) ratios of 1:2.5 superplasticizers (SP), 1:3.0 SP and 1:3.5 SP was also employed. Fixed water to cement (w/c) ratio of 0.5 was used. The samples were water cured and the assessment of the strength performance of mortar cubes carried out at 7 and 28 days. Studies conducted have shown that WGWP has good pozzolanic properties. In term of compressive strength, it was observed that employing C:S ratio of 1:3.5 SP is better than 1:2.5 SP and 1:3.0 SP.
Suatu kajian mengenai Indeks Kualiti Air (IKA) telah dijalankan di lembangan Sungai Paka, Terengganu. Ianya melibatkan pengukuran oksigen terlarut, pH, permintaan oksigen biokimia, permintaan oksigen kimia, jumlah pepejal terampai dan ammonia di lapan buah stesen pensampelan. Hasil kajian menunjukkan semua stesen pensampelan berada dalam status bersih kecuali dua stesen tercemar yang terletak di Sungai Rengat dan Sungai Rasau. Walau bagaimanapun, secara keseluruhannya purata nilai IKA bagi lembangan Sungai Paka adalah 72.4% dan boleh diklasifikasikan sebagai kelas II dengan status sedikit tercemar. Hasil kajian juga menunjukkan kumbahan daripada kilang kelapa sawit merupakan penyumbang utama kepada kemerosotan nilai IKA di kawasan kajian.
Diverting waste material from landfill sites has a big implication for the creation of new markets and has environmental benefits through offsetting the need for the extraction of raw materials. Besides, the major attention especially in construction industry is the problem to make natural resources sustainable for three to four decades in future. However, in this study finely glass powder with pozzolanic properties is found to be a partial replacement for cement and can acts as filler in the microstructure of a mortar block. Thus, a study was conducted to see the effects of various proportions of windscreen glass waste powder (WGWP) in determining the degree of water absorption on mortar incorporated with WGWP and to determine the optimum replacement to the ordinary Portland cement (OPC) with WGWP. Several compositions of WGWP (0%, 5%, 10%, 15% and 20% by cement weight) of mortar cube sample were prepared and cured at 7, 28 and 60 days to undergo a water absorption test. From this research, it shows that the use of WGWP was found to be the best features pozzolanic enough to use as a partial replacement for cement and it can reduced the pores of mortar by blocking the large voids in the hydrated cement paste through pozzolanic reaction. In the term of water absorption, the lowest reading was achieved in 15% and it can be said that 15% replacement is the optimum replacement of OPC.