Affiliations 

  • 1 Chemical Engineering Department, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia; HICoE-Centre for Biofuel and Biochemical Research, Institute of Sustainable Energy, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia
  • 2 Chemical Engineering Department, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia; HICoE-Centre for Biofuel and Biochemical Research, Institute of Sustainable Energy, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia. Electronic address: [email protected]
  • 3 HICoE-Centre for Biofuel and Biochemical Research, Institute of Sustainable Energy, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia; Fundamental and Applied Sciences Department, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia
  • 4 Department of Chemistry, Faculty of Science, Centre for Sustainable Nanomaterials, Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310, Johor Bahru, Johor, Malaysia
  • 5 Centre for Urban Resource Sustainability, Institute of Smart and Sustainable Living, Department of Civil and Environmental Engineering, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia
  • 6 Department of Chemical and Energy Engineering, Faculty of Engineering and Science, Curtin University Malaysia, CDT250, 98009, Miri, Sarawak, Malaysia
  • 7 Department of Chemical Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, 43000, Selangor, Malaysia
  • 8 NUS Environmental Research Institute, National University of Singapore, 1 Create Way, Create Tower, #15-02, 138602, Singapore, Singapore; Energy and Environmental Sustainability Solutions for Megacities (E2S2), Campus for Research Excellence and Technological Enterprise (CREATE), 138602, Singapore, Singapore
  • 9 Department of Engineering and Chemical Sciences, Karlstad University, Sweden
J Environ Manage, 2024 May 02;359:120988.
PMID: 38701587 DOI: 10.1016/j.jenvman.2024.120988

Abstract

Microalgae demonstrate significant potential as a source of liquid-based biofuels. However, increasing biomass productivity in existing cultivation systems is a critical prerequisite for their successful integration into large-scale operations. Thus, the current work aimed to accelerate the growth of C. vulgaris via exogenous supplementation of biostimulant derived from onion peel waste. Under the optimal growth conditions, which entailed a biostimulant dosage of 37.5% v/v, a pH of 3, an air flow rate of 0.4 L/min, and a 2% v/v inoculum harvested during the mid-log phase, yielded a maximum biomass concentration of 1.865 g/L. Under the arbitrarily optimized parameters, a comparable growth pattern was evident in the upscaled cultivation of C. vulgaris, underscoring the potential commercial viability of the biostimulant. The biostimulant, characterized through gas chromatography-mass spectrometry (GC-MS) analysis, revealed a composition rich in polyphenolic and organo-sulphur compounds, notably including allyl trisulfide (28.13%), methyl allyl trisulfide (23.04%), and allyl disulfide (20.78%), showcasing potent antioxidant properties. Additionally, microalgae treated with the biostimulant consistently retained their lipid content at 18.44% without any significant reduction. Furthermore, a significant rise in saturated fatty acid (SFA) content was observed, with C16:0 and C18:1 dominating both bench-scale (44.08% and 14.01%) and upscaled (51.12% and 13.07%) microalgae cultures, in contrast to the control group where C18:2 was prevalent. Consequently, SFA contents reached 54.35% and 65.43% in bench-scale and upscaled samples respectively, compared to 33.73% in the control culture. These compositional characteristics align well with the requirements for producing high-quality crude biodiesel.

* Title and MeSH Headings from MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine.